[(silox)(2)ReO](2) (silox = (Bu3SiO)-Bu-t) contains a Re equivalent to Re bond and terminal oxo ligands

R E  Douthwaite; P T  Wolczanski; E  Merschrod

[(silox)(2)ReO](2) (silox = (Bu3SiO)-Bu-t) contains a Re equivalent to Re bond and terminal oxo ligands

R E Douthwaite, P T Wolczanski, E Merschrod

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The preference for terminal rather than bridging {i.e. [(silox)(2)Re](2)(mu-O)(2)} oxo ligands in C-2 (silox)(2)(O)Re=Re(O)(silox)(2) is electronic, not steric, in origin.

Original language	English
Pages (from-to)	2591-2592
Number of pages	2
Journal	Chemical Communications
Issue number	23
Publication status	Published - 7 Dec 1998

Keywords

COMPLEXES
CHEMISTRY
TUNGSTEN
HYDRIDES

Cite this

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title = "[(silox)(2)ReO](2) (silox = (Bu3SiO)-Bu-t) contains a Re equivalent to Re bond and terminal oxo ligands",

abstract = "The preference for terminal rather than bridging {i.e. [(silox)(2)Re](2)(mu-O)(2)} oxo ligands in C-2 (silox)(2)(O)Re=Re(O)(silox)(2) is electronic, not steric, in origin.",

keywords = "COMPLEXES, CHEMISTRY, TUNGSTEN, HYDRIDES",

author = "Douthwaite, {R E} and Wolczanski, {P T} and E Merschrod",

year = "1998",

month = dec,

day = "7",

language = "English",

pages = "2591--2592",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - [(silox)(2)ReO](2) (silox = (Bu3SiO)-Bu-t) contains a Re equivalent to Re bond and terminal oxo ligands

AU - Douthwaite, R E

AU - Wolczanski, P T

AU - Merschrod, E

PY - 1998/12/7

Y1 - 1998/12/7

N2 - The preference for terminal rather than bridging {i.e. [(silox)(2)Re](2)(mu-O)(2)} oxo ligands in C-2 (silox)(2)(O)Re=Re(O)(silox)(2) is electronic, not steric, in origin.

AB - The preference for terminal rather than bridging {i.e. [(silox)(2)Re](2)(mu-O)(2)} oxo ligands in C-2 (silox)(2)(O)Re=Re(O)(silox)(2) is electronic, not steric, in origin.

KW - COMPLEXES

KW - CHEMISTRY

KW - TUNGSTEN

KW - HYDRIDES

M3 - Article

SN - 1359-7345

SP - 2591

EP - 2592

JO - Chemical Communications

JF - Chemical Communications

IS - 23

ER -