Solid acids for green chemistry

J H  Clark

doi:10.1021/ar010072a

Solid acids for green chemistry

J H Clark

Chemistry

Research output: Contribution to journal › Literature review › peer-review

Abstract

Solid acids and especially those based on micelle-templated silicas and other mesoporous high surface area support materials are beginning to play a significant role in the greening of fine and speciality chemicals manufacturing processes. A wide range of important organic reactions can be efficiently catalyzed by these materials, which can be designed to provide different types of acidity as well as high degrees of reaction selectivity. The solid acids generally have high turnover numbers and can be easily separated from the organic components. The combination of this chemistry with innovative reaction engineering offers exciting opportunities for innovative green chemical manufacturing in the future.

Original language	English
Pages (from-to)	791-797
Number of pages	7
Journal	ACCOUNTS OF CHEMICAL RESEARCH
Volume	35
Issue number	9
DOIs	https://doi.org/10.1021/ar010072a
Publication status	Published - Sept 2002

Keywords

SUPPORTED ALUMINUM-CHLORIDE
ENHANCED SELECTIVITY
LINEAR ALKYLBENZENES
CATALYSIS
REAGENTS
ALKYLATION
ROUTE

Access to Document

10.1021/ar010072a

Cite this

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title = "Solid acids for green chemistry",

abstract = "Solid acids and especially those based on micelle-templated silicas and other mesoporous high surface area support materials are beginning to play a significant role in the greening of fine and speciality chemicals manufacturing processes. A wide range of important organic reactions can be efficiently catalyzed by these materials, which can be designed to provide different types of acidity as well as high degrees of reaction selectivity. The solid acids generally have high turnover numbers and can be easily separated from the organic components. The combination of this chemistry with innovative reaction engineering offers exciting opportunities for innovative green chemical manufacturing in the future.",

keywords = "SUPPORTED ALUMINUM-CHLORIDE, ENHANCED SELECTIVITY, LINEAR ALKYLBENZENES, CATALYSIS, REAGENTS, ALKYLATION, ROUTE",

author = "Clark, {J H}",

year = "2002",

month = sep,

doi = "10.1021/ar010072a",

language = "English",

volume = "35",

pages = "791--797",

journal = "ACCOUNTS OF CHEMICAL RESEARCH",

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publisher = "American Chemical Society",

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AU - Clark, J H

PY - 2002/9

Y1 - 2002/9

N2 - Solid acids and especially those based on micelle-templated silicas and other mesoporous high surface area support materials are beginning to play a significant role in the greening of fine and speciality chemicals manufacturing processes. A wide range of important organic reactions can be efficiently catalyzed by these materials, which can be designed to provide different types of acidity as well as high degrees of reaction selectivity. The solid acids generally have high turnover numbers and can be easily separated from the organic components. The combination of this chemistry with innovative reaction engineering offers exciting opportunities for innovative green chemical manufacturing in the future.

AB - Solid acids and especially those based on micelle-templated silicas and other mesoporous high surface area support materials are beginning to play a significant role in the greening of fine and speciality chemicals manufacturing processes. A wide range of important organic reactions can be efficiently catalyzed by these materials, which can be designed to provide different types of acidity as well as high degrees of reaction selectivity. The solid acids generally have high turnover numbers and can be easily separated from the organic components. The combination of this chemistry with innovative reaction engineering offers exciting opportunities for innovative green chemical manufacturing in the future.

KW - SUPPORTED ALUMINUM-CHLORIDE

KW - ENHANCED SELECTIVITY

KW - LINEAR ALKYLBENZENES

KW - CATALYSIS

KW - REAGENTS

KW - ALKYLATION

KW - ROUTE

U2 - 10.1021/ar010072a

DO - 10.1021/ar010072a

M3 - Literature review

SN - 0001-4842

VL - 35

SP - 791

EP - 797

JO - ACCOUNTS OF CHEMICAL RESEARCH

JF - ACCOUNTS OF CHEMICAL RESEARCH

IS - 9

ER -