Spatially resolved variations in reflectivity across iron oxide thin films

TY - JOUR

T1 - Spatially resolved variations in reflectivity across iron oxide thin films

AU - Kelley, Christopher Stephen

AU - Thompson, Sarah Madeleine

AU - Gilks, Daniel

AU - Sizeland, James

AU - Lari, Leonardo

AU - Lazarov, Vlado

AU - Matsuzaki, Kosuke

AU - LeFrancois, Stephane

AU - Cinque, Gianfelice

AU - Dumas, Paul

N1 - Publisher Copyright: © 2017 The Authors Copyright: Copyright 2017 Elsevier B.V., All rights reserved.

PY - 2017/11/1

Y1 - 2017/11/1

N2 - The spin polarising properties of the iron oxide magnetite (Fe3O4) make it attractive for use in spintronic devices, but its sensitivity to compositional and structural variations make it challenging to prepare reli- ably. Infrared microspectroscopy and modelling are used to determine the spatial variation in the chem- ical composition of three thin films of iron oxide; one prepared by pulsed laser deposition (PLD), one by molecular beam epitaxy (MBE) deposition of iron whilst simultaneously flowing oxygen into the chamber and one by flowing oxygen only once deposition is complete. The technique is easily able to distinguish between films which contain metallic iron and different iron oxide phases as well as spatial variations in composition across the films. The film grown by post-oxidising iron is spatially uniform but not fully oxi- dised, the film grown by simultaneously oxidising iron showed spatial variation in oxide composition while the film grown by PLD was spatially uniform magnetite.

AB - The spin polarising properties of the iron oxide magnetite (Fe3O4) make it attractive for use in spintronic devices, but its sensitivity to compositional and structural variations make it challenging to prepare reli- ably. Infrared microspectroscopy and modelling are used to determine the spatial variation in the chem- ical composition of three thin films of iron oxide; one prepared by pulsed laser deposition (PLD), one by molecular beam epitaxy (MBE) deposition of iron whilst simultaneously flowing oxygen into the chamber and one by flowing oxygen only once deposition is complete. The technique is easily able to distinguish between films which contain metallic iron and different iron oxide phases as well as spatial variations in composition across the films. The film grown by post-oxidising iron is spatially uniform but not fully oxi- dised, the film grown by simultaneously oxidising iron showed spatial variation in oxide composition while the film grown by PLD was spatially uniform magnetite.

KW - Infrared

KW - Magnetoresistance

KW - Oxides

KW - Spintronics

UR - http://www.scopus.com/inward/record.url?scp=85021187715&partnerID=8YFLogxK

U2 - 10.1016/j.jmmm.2017.04.004

DO - 10.1016/j.jmmm.2017.04.004

M3 - Article

SN - 0304-8853

VL - 441

SP - 743

EP - 749

JO - Journal of Magnetism and Magnetic Materials

JF - Journal of Magnetism and Magnetic Materials

ER -