Spectrum of hot water in the 2000-4750 cm(-1) frequency range

Nikolai F. Zobov; Sergei V. Shirin; Oleg L. Polyansky; Robert J. Barber; Jonathan Tennyson; Pierre-Francois Coheur; Peter F. Bernath; Michel Carleer; Reginald Colin

doi:10.1016/j.jms.2006.03.001

Spectrum of hot water in the 2000-4750 cm(-1) frequency range

Nikolai F. Zobov, Sergei V. Shirin, Oleg L. Polyansky, Robert J. Barber, Jonathan Tennyson, Pierre-Francois Coheur, Peter F. Bernath, Michel Carleer, Reginald Colin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

An emission Spectrum recorded in an oxyacetylene torch [P.-F. Coheur, P.F. Bernath, M. Carleer, R. Colin, O.L. Polyansky, N.F. Zobov, S.V. Shirin, R.J. Barber, J. Tennyson, J. Chem. Phys. 122 (2005) 074307] is analyzed for the region covering stretching fundamentals and associated hot bands of water. Many lines could be assigned on the basis of previously determined energy levels. New assignments made with a new variational linelist allow a further 800 energy levels covering 15 vibrational states and rotations up to J = 32 to be assigned. A simultaneous re-analysis of previously reported sunspot absorption spectra leads to the assignment of 581 further lines in the L-band spectrum and 67 in the N-band spectrum. (C) 2006 Elsevier Inc. All rights reserved.

Original language	English
Pages (from-to)	115-122
Number of pages	8
Journal	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume	237
Issue number	1
DOIs	https://doi.org/10.1016/j.jms.2006.03.001
Publication status	Published - May 2006

Keywords

water vapor
line assignments
sunspots
HYDROGEN FLAME SPECTRA
RO-VIBRATIONAL LEVELS
BAND SPECTRUM
SUN
SPECTROSCOPY
TRANSITIONS
MOLECULE
SUNSPOT
CM-1

Access to Document

10.1016/j.jms.2006.03.001

Cite this

@article{fd5b2b91e0cd417793412edd925f98cd,

title = "Spectrum of hot water in the 2000-4750 cm(-1) frequency range",

abstract = "An emission Spectrum recorded in an oxyacetylene torch [P.-F. Coheur, P.F. Bernath, M. Carleer, R. Colin, O.L. Polyansky, N.F. Zobov, S.V. Shirin, R.J. Barber, J. Tennyson, J. Chem. Phys. 122 (2005) 074307] is analyzed for the region covering stretching fundamentals and associated hot bands of water. Many lines could be assigned on the basis of previously determined energy levels. New assignments made with a new variational linelist allow a further 800 energy levels covering 15 vibrational states and rotations up to J = 32 to be assigned. A simultaneous re-analysis of previously reported sunspot absorption spectra leads to the assignment of 581 further lines in the L-band spectrum and 67 in the N-band spectrum. (C) 2006 Elsevier Inc. All rights reserved.",

keywords = "water vapor, line assignments, sunspots, HYDROGEN FLAME SPECTRA, RO-VIBRATIONAL LEVELS, BAND SPECTRUM, SUN, SPECTROSCOPY, TRANSITIONS, MOLECULE, SUNSPOT, CM-1",

author = "Zobov, {Nikolai F.} and Shirin, {Sergei V.} and Polyansky, {Oleg L.} and Barber, {Robert J.} and Jonathan Tennyson and Pierre-Francois Coheur and Bernath, {Peter F.} and Michel Carleer and Reginald Colin",

year = "2006",

month = may,

doi = "10.1016/j.jms.2006.03.001",

language = "English",

volume = "237",

pages = "115--122",

journal = "JOURNAL OF MOLECULAR SPECTROSCOPY",

issn = "0022-2852",

publisher = "Academic Press",

number = "1",

}

TY - JOUR

T1 - Spectrum of hot water in the 2000-4750 cm(-1) frequency range

AU - Zobov, Nikolai F.

AU - Shirin, Sergei V.

AU - Polyansky, Oleg L.

AU - Barber, Robert J.

AU - Tennyson, Jonathan

AU - Coheur, Pierre-Francois

AU - Bernath, Peter F.

AU - Carleer, Michel

AU - Colin, Reginald

PY - 2006/5

Y1 - 2006/5

N2 - An emission Spectrum recorded in an oxyacetylene torch [P.-F. Coheur, P.F. Bernath, M. Carleer, R. Colin, O.L. Polyansky, N.F. Zobov, S.V. Shirin, R.J. Barber, J. Tennyson, J. Chem. Phys. 122 (2005) 074307] is analyzed for the region covering stretching fundamentals and associated hot bands of water. Many lines could be assigned on the basis of previously determined energy levels. New assignments made with a new variational linelist allow a further 800 energy levels covering 15 vibrational states and rotations up to J = 32 to be assigned. A simultaneous re-analysis of previously reported sunspot absorption spectra leads to the assignment of 581 further lines in the L-band spectrum and 67 in the N-band spectrum. (C) 2006 Elsevier Inc. All rights reserved.

AB - An emission Spectrum recorded in an oxyacetylene torch [P.-F. Coheur, P.F. Bernath, M. Carleer, R. Colin, O.L. Polyansky, N.F. Zobov, S.V. Shirin, R.J. Barber, J. Tennyson, J. Chem. Phys. 122 (2005) 074307] is analyzed for the region covering stretching fundamentals and associated hot bands of water. Many lines could be assigned on the basis of previously determined energy levels. New assignments made with a new variational linelist allow a further 800 energy levels covering 15 vibrational states and rotations up to J = 32 to be assigned. A simultaneous re-analysis of previously reported sunspot absorption spectra leads to the assignment of 581 further lines in the L-band spectrum and 67 in the N-band spectrum. (C) 2006 Elsevier Inc. All rights reserved.

KW - water vapor

KW - line assignments

KW - sunspots

KW - HYDROGEN FLAME SPECTRA

KW - RO-VIBRATIONAL LEVELS

KW - BAND SPECTRUM

KW - SUN

KW - SPECTROSCOPY

KW - TRANSITIONS

KW - MOLECULE

KW - SUNSPOT

KW - CM-1

U2 - 10.1016/j.jms.2006.03.001

DO - 10.1016/j.jms.2006.03.001

M3 - Article

SN - 0022-2852

VL - 237

SP - 115

EP - 122

JO - JOURNAL OF MOLECULAR SPECTROSCOPY

JF - JOURNAL OF MOLECULAR SPECTROSCOPY

IS - 1

ER -