Spin trapping of radical intermediates in gas phase catalysis: cyclohexane oxidation over metal oxides

Marco Conte, Victor Chechik

Research output: Contribution to journalArticlepeer-review

Abstract

The formation of radicals in the gas phase oxidation of cyclohexane over metal oxides was studied using spin trapping and EPR spectroscopy; the results confirmed that during the catalytic initiation, the oxygen responsible for the radicals formation originates from the lattice of the metal oxide.

Original languageEnglish
Pages (from-to)3991-3993
Number of pages3
JournalChemical Communications
Volume46
Issue number22
DOIs
Publication statusPublished - 14 Jun 2010

Keywords

  • SELECTIVE OXIDATION
  • CIGARETTE-SMOKE
  • RESONANCE
  • LIQUID
  • MOO3
  • REDUCTION
  • MECHANISM
  • DEFECTS
  • SPECTRA
  • PROPENE

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