Structures of [Co(II)(L)(NO3)(HOCH3)(n)]BPh4 (n = 4,5) complexes (L = cis,cis-1,3,5-triaminocyclohexane-based ligand): Structural 'snapshots' of anion binding to a metal centre

Clive J. Boxwell, Paul H. Walton*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The crystal structures of [Co(II)(L)(NO3)(HOCH3)(n)]BPh4{L = cis,cis-1,3,5-tri[(4-tert-butylphenyl)propenylideneamino]cyclohexane} complexes demonstrate the role of solvent molecules in the stabilisation of anions within a solvated cavity: the structures can be compared with bicarbonate binding in the active site of carbonic anhydrase.

Original languageEnglish
Pages (from-to)1647-1648
Number of pages2
JournalChemical Communications
Issue number17
DOIs
Publication statusPublished - 7 Sept 1999

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