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Suzuki-Miyaura cross-coupling of alkenyl tosylates with alkenyl MIDA boronates

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Publication details

JournalTetrahedron Letters
DatePublished - 4 Jul 2012
Issue number27
Number of pages4
Pages (from-to)3444-3447
Original languageEnglish


A practical procedure for the palladium-catalysed Suzuki-Miyaura coupling of various alkenyl tosylates with alkenyl MIDA boronates has been developed. Commercially available trans-bromo[N-succinimidyl-bis(triphenylphosphine)Ipalladium(II) [Pd(PPh3)(2)NBS] is an effective catalyst under the slow release conditions of MIDA boronates; with less activated alkenyl tosylates addition of the cheap, air-stable tricyclohexylphosphine tetrafluoroborate enhances reactivity. (C) 2012 Elsevier Ltd. All rights reserved.

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