Synthesis and characterization of nanoporous phospho-tungstate organic - inorganic hybrid materials

Katabathini Narasimha Rao; Lee D. Dingwall; Pratibha L. Gai; Adam F. Lee; Stewart J. Tavener; Nigel A. Young; Karen Wilson

doi:10.1039/b715826b

Synthesis and characterization of nanoporous phospho-tungstate organic - inorganic hybrid materials

Katabathini Narasimha Rao, Lee D. Dingwall, Pratibha L. Gai, Adam F. Lee, Stewart J. Tavener, Nigel A. Young, Karen Wilson

Research output: Contribution to journal › Article › peer-review

Abstract

Nanoporous phospho-tungstate organic - inorganic hybrid materials have been synthesized from sodium tungstate and mono-n-dodecyl phosphate (MDP), which was used as both surfactant and phosphorus precursor. These hybrid materials were thoroughly characterized by N-2 adsorption, elemental analysis, powder XRD, FTIR, Raman, TG, TEM and XPS and possess lamellar structures with interlayer spacings of 3.2 nm. A plausible method for formation of hybrid materials comprised of lacunary Keggin anions and micelles of surfactants is proposed.

Original language	English
Pages (from-to)	868-874
Number of pages	7
Journal	Journal of Materials Chemistry
Volume	18
Issue number	8
DOIs	https://doi.org/10.1039/b715826b
Publication status	Published - 2008

Keywords

PROTON-EXCHANGE MEMBRANES
HETEROPOLY COMPOUNDS
SURFACTANT
ANIONS
OXIDE

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10.1039/b715826b

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abstract = "Nanoporous phospho-tungstate organic - inorganic hybrid materials have been synthesized from sodium tungstate and mono-n-dodecyl phosphate (MDP), which was used as both surfactant and phosphorus precursor. These hybrid materials were thoroughly characterized by N-2 adsorption, elemental analysis, powder XRD, FTIR, Raman, TG, TEM and XPS and possess lamellar structures with interlayer spacings of 3.2 nm. A plausible method for formation of hybrid materials comprised of lacunary Keggin anions and micelles of surfactants is proposed.",

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author = "Rao, {Katabathini Narasimha} and Dingwall, {Lee D.} and Gai, {Pratibha L.} and Lee, {Adam F.} and Tavener, {Stewart J.} and Young, {Nigel A.} and Karen Wilson",

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doi = "10.1039/b715826b",

language = "English",

volume = "18",

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T1 - Synthesis and characterization of nanoporous phospho-tungstate organic - inorganic hybrid materials

AU - Rao, Katabathini Narasimha

AU - Dingwall, Lee D.

AU - Gai, Pratibha L.

AU - Lee, Adam F.

AU - Tavener, Stewart J.

AU - Young, Nigel A.

AU - Wilson, Karen

PY - 2008

Y1 - 2008

N2 - Nanoporous phospho-tungstate organic - inorganic hybrid materials have been synthesized from sodium tungstate and mono-n-dodecyl phosphate (MDP), which was used as both surfactant and phosphorus precursor. These hybrid materials were thoroughly characterized by N-2 adsorption, elemental analysis, powder XRD, FTIR, Raman, TG, TEM and XPS and possess lamellar structures with interlayer spacings of 3.2 nm. A plausible method for formation of hybrid materials comprised of lacunary Keggin anions and micelles of surfactants is proposed.

AB - Nanoporous phospho-tungstate organic - inorganic hybrid materials have been synthesized from sodium tungstate and mono-n-dodecyl phosphate (MDP), which was used as both surfactant and phosphorus precursor. These hybrid materials were thoroughly characterized by N-2 adsorption, elemental analysis, powder XRD, FTIR, Raman, TG, TEM and XPS and possess lamellar structures with interlayer spacings of 3.2 nm. A plausible method for formation of hybrid materials comprised of lacunary Keggin anions and micelles of surfactants is proposed.

KW - PROTON-EXCHANGE MEMBRANES

KW - HETEROPOLY COMPOUNDS

KW - SURFACTANT

KW - ANIONS

KW - OXIDE

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EP - 874

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 8

ER -

Synthesis and characterization of nanoporous phospho-tungstate organic - inorganic hybrid materials

Abstract

Keywords

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