Abstract
Direct reaction of [Zn(OH)(L)](+), L = cis, cis-1,3,5-tris[(E, E)3-( 2-furyl) acrylideneamino] cyclohexane, with methanol gives a mixture of the starting material and [ Zn(OMe)(L)](+); structural analysis of the complexes shows that they are models of reactive intermediates in the catalytic cycles of the zinc enzymes carbonic anhydrase and liver alcohol dehydrogenase.
Original language | English |
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Pages (from-to) | 1572-1573 |
Number of pages | 2 |
Journal | Chemical Communications |
Volume | 13 |
Issue number | 13 |
DOIs | |
Publication status | Published - 2003 |
Keywords
- ZINC PYRAZOLYLBORATE COMPLEXES
- HYDROXIDE COMPLEX
- PHENOXIDE
- DIOXIDE
- LIGAND