By the same authors

From the same journal

Synthesis of 3-Alkyl-4-(chloromethyl)-1-RSO2-1H-pyrrol-2(5H)-ones, Using a Sequential ATRC/[1,2]-Elimination, from 2,2-Dichloro-N-(2-chloroallyl)-N-RSO2-amides

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Published copy (DOI)

Author(s)

  • Matteo Bregoli
  • Fulvia Felluga
  • Vincenzo Frenna
  • Franco Ghelfi
  • Ugo M. Pagnoni
  • Andrew F. Parsons
  • Giovanni Petrillo
  • Domenico Spinelli

Department/unit(s)

Publication details

JournalSYNTHESIS-STUTTGART
DatePublished - Apr 2011
Issue number8
Number of pages12
Pages (from-to)1267-1278
Original languageEnglish

Abstract

The preparation of 3-alkyl-4-(chloromethyl)-1-RSO2-1H- pyrrol-2(5H)-ones was efficiently accomplished through a [1,2]-elimination of gamma-lactams derived from the copper(I)-catalysed ATRC of 2,2-dichloro-N-(2-chloroallyl)-N-RSO2-amides. The two reactions can be integrated into a sequential one-pot process.

    Research areas

  • copper, cyclization, elimination, lactams, radical reaction, TRANSFER RADICAL CYCLIZATIONS, ATOM-TRANSFER CYCLIZATION, FORMAL TOTAL-SYNTHESIS, CHAETOMELLIC ANHYDRIDE-A, BOND-FORMING REACTIONS, GAMMA-LACTAMS, FUNCTIONAL REARRANGEMENT, AMMONIA SYNTHON, N-ALLYLTRICHLOROACETAMIDES, CATALYZED CYCLIZATION

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