Synthesis of bispyrrolidines by radical cyclisation of diallylamines using phosphorus hydrides

Andrew F. Parsons; Anthony Wright

doi:10.1055/s-2008-1072789

Synthesis of bispyrrolidines by radical cyclisation of diallylamines using phosphorus hydrides

Andrew F. Parsons, Anthony Wright

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Sequential radical addition-cyclisation reactions of diallylamines using either hypophosphorous acid or a bisphosphinothioate are shown to afford bispyrrolidines in good to excellent yields.

Original language	English
Pages (from-to)	2142-2146
Number of pages	5
Journal	Synlett
Issue number	14
DOIs	https://doi.org/10.1055/s-2008-1072789
Publication status	Published - 22 Aug 2008

Keywords

addition reactions
cyclisations
phosphorus
radical reactions
CARBON BOND FORMATION
EMMONS-TYPE REACTIONS
CENTERED RADICALS
PHOSPHINIC ACID
ENANTIOSELECTIVE ADDITION
STEREOSELECTIVE-SYNTHESIS
ALLYLIC TRICHLOROSILANES
DERIVATIVES
ANALOGS
AGENTS

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title = "Synthesis of bispyrrolidines by radical cyclisation of diallylamines using phosphorus hydrides",

abstract = "Sequential radical addition-cyclisation reactions of diallylamines using either hypophosphorous acid or a bisphosphinothioate are shown to afford bispyrrolidines in good to excellent yields.",

keywords = "addition reactions, cyclisations, phosphorus, radical reactions, CARBON BOND FORMATION, EMMONS-TYPE REACTIONS, CENTERED RADICALS, PHOSPHINIC ACID, ENANTIOSELECTIVE ADDITION, STEREOSELECTIVE-SYNTHESIS, ALLYLIC TRICHLOROSILANES, DERIVATIVES, ANALOGS, AGENTS",

author = "Parsons, {Andrew F.} and Anthony Wright",

year = "2008",

month = aug,

day = "22",

doi = "10.1055/s-2008-1072789",

language = "English",

pages = "2142--2146",

journal = "Synlett",

issn = "1437-2096",

publisher = "Georg Thieme Verlag",

number = "14",

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TY - JOUR

T1 - Synthesis of bispyrrolidines by radical cyclisation of diallylamines using phosphorus hydrides

AU - Parsons, Andrew F.

AU - Wright, Anthony

PY - 2008/8/22

Y1 - 2008/8/22

N2 - Sequential radical addition-cyclisation reactions of diallylamines using either hypophosphorous acid or a bisphosphinothioate are shown to afford bispyrrolidines in good to excellent yields.

AB - Sequential radical addition-cyclisation reactions of diallylamines using either hypophosphorous acid or a bisphosphinothioate are shown to afford bispyrrolidines in good to excellent yields.

KW - addition reactions

KW - cyclisations

KW - phosphorus

KW - radical reactions

KW - CARBON BOND FORMATION

KW - EMMONS-TYPE REACTIONS

KW - CENTERED RADICALS

KW - PHOSPHINIC ACID

KW - ENANTIOSELECTIVE ADDITION

KW - STEREOSELECTIVE-SYNTHESIS

KW - ALLYLIC TRICHLOROSILANES

KW - DERIVATIVES

KW - ANALOGS

KW - AGENTS

UR - http://www.scopus.com/inward/record.url?scp=51149094775&partnerID=8YFLogxK

U2 - 10.1055/s-2008-1072789

DO - 10.1055/s-2008-1072789

M3 - Article

SN - 1437-2096

SP - 2142

EP - 2146

JO - Synlett

JF - Synlett

IS - 14

ER -

Synthesis of bispyrrolidines by radical cyclisation of diallylamines using phosphorus hydrides

Abstract

Keywords

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