Synthesis of constrained-geometry chiral Di-N-heterocyclic carbene ligands and their silver(I) and palladium(II) complexes

L G  Bonnet; R E  Douthwaite; R  Hodgson

doi:10.1021/om030527v

Synthesis of constrained-geometry chiral Di-N-heterocyclic carbene ligands and their silver(I) and palladium(II) complexes

L G Bonnet, R E Douthwaite, R Hodgson

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Silver(I) and palladium(II) complexes of constrained-geometry chiral di-N-heterocyclic carbenes have been prepared from trans-1,2-diaminocyclohexane via the base-induced 1,3-cycloaddition of tosylmethyl isocyanide to diimines.

Original language	English
Pages (from-to)	4384-4386
Number of pages	3
Journal	Organometallics
Volume	22
Issue number	22
DOIs	https://doi.org/10.1021/om030527v
Publication status	Published - 27 Oct 2003

Keywords

TRANSITION-METAL-COMPLEXES
ASYMMETRIC CATALYSIS
CONJUGATE ADDITION
IMIDAZOLIUM SALTS
OLEFIN METATHESIS
HYDROGENATION
AIR

Access to Document

10.1021/om030527v

Cite this

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abstract = "Silver(I) and palladium(II) complexes of constrained-geometry chiral di-N-heterocyclic carbenes have been prepared from trans-1,2-diaminocyclohexane via the base-induced 1,3-cycloaddition of tosylmethyl isocyanide to diimines.",

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author = "Bonnet, {L G} and Douthwaite, {R E} and R Hodgson",

year = "2003",

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language = "English",

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AU - Bonnet, L G

AU - Douthwaite, R E

AU - Hodgson, R

PY - 2003/10/27

Y1 - 2003/10/27

N2 - Silver(I) and palladium(II) complexes of constrained-geometry chiral di-N-heterocyclic carbenes have been prepared from trans-1,2-diaminocyclohexane via the base-induced 1,3-cycloaddition of tosylmethyl isocyanide to diimines.

AB - Silver(I) and palladium(II) complexes of constrained-geometry chiral di-N-heterocyclic carbenes have been prepared from trans-1,2-diaminocyclohexane via the base-induced 1,3-cycloaddition of tosylmethyl isocyanide to diimines.

KW - TRANSITION-METAL-COMPLEXES

KW - ASYMMETRIC CATALYSIS

KW - CONJUGATE ADDITION

KW - IMIDAZOLIUM SALTS

KW - OLEFIN METATHESIS

KW - HYDROGENATION

KW - AIR

U2 - 10.1021/om030527v

DO - 10.1021/om030527v

M3 - Article

SN - 0276-7333

VL - 22

SP - 4384

EP - 4386

JO - Organometallics

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ER -