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Synthesis of Cyclic Carbonates Catalysed by Chromium and Aluminium Salphen Complexes

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JournalChemistry : A European Journal (Weinheim an der Bergstrasse, Germany)
DatePublished - 5 Feb 2016
Issue number6
Volume22
Number of pages8
Pages (from-to)2100-2107
Original languageEnglish

Abstract

Chromium and aluminium salphen complexes have been found to display remarkable catalytic activity in the synthesis of cyclic carbonates from a range of epoxides and carbon dioxide. The Al(salphen) complex is more reactive towards terminal epoxides at ambient temperature and pressure, whereas the Cr(salphen) complex exhibits higher catalytic activity towards more challenging internal epoxides at elevated temperature and pressure.

    Research areas

  • aluminium, chromium, cyclic carbonates, epoxides, homogeneous catalysis, salphen ligands

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