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From the same journal

Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation

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Published copy (DOI)

Author(s)

  • Petr Slavík
  • Michal Kohout
  • Stanislav Böhm
  • Václav Eigner
  • Pavel Lhoták

Department/unit(s)

Publication details

JournalChemical Communications
DateAccepted/In press - 21 Dec 2015
DateE-pub ahead of print - 21 Dec 2015
DatePublished (current) - 7 Feb 2016
Issue number11
Volume52
Number of pages4
Pages (from-to)2366-2369
Early online date21/12/15
Original languageEnglish

Abstract

Direct mercuration of calix[4]arene immobilized in the partial cone conformation led to the meta-substituted isomer which was subsequently subjected to Pd-catalysed coupling (C-H activation) with the neighbouring aromatic subunit. Regioselective mercuration thus enabled access to a novel type of inherently chiral calixarenes with a highly distorted cavity potentially applicable to the design of new chiral receptors.

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