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Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation

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Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation. / Slavík, Petr; Kohout, Michal; Böhm, Stanislav; Eigner, Václav; Lhoták, Pavel.

In: Chemical Communications, Vol. 52, No. 11, 07.02.2016, p. 2366-2369.

Research output: Contribution to journalArticlepeer-review

Harvard

Slavík, P, Kohout, M, Böhm, S, Eigner, V & Lhoták, P 2016, 'Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation', Chemical Communications, vol. 52, no. 11, pp. 2366-2369. https://doi.org/10.1039/c5cc09388k

APA

Slavík, P., Kohout, M., Böhm, S., Eigner, V., & Lhoták, P. (2016). Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation. Chemical Communications, 52(11), 2366-2369. https://doi.org/10.1039/c5cc09388k

Vancouver

Slavík P, Kohout M, Böhm S, Eigner V, Lhoták P. Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation. Chemical Communications. 2016 Feb 7;52(11):2366-2369. https://doi.org/10.1039/c5cc09388k

Author

Slavík, Petr ; Kohout, Michal ; Böhm, Stanislav ; Eigner, Václav ; Lhoták, Pavel. / Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation. In: Chemical Communications. 2016 ; Vol. 52, No. 11. pp. 2366-2369.

Bibtex - Download

@article{430146392ba44e3598a83137345b2ecf,
title = "Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation",
abstract = "Direct mercuration of calix[4]arene immobilized in the partial cone conformation led to the meta-substituted isomer which was subsequently subjected to Pd-catalysed coupling (C-H activation) with the neighbouring aromatic subunit. Regioselective mercuration thus enabled access to a novel type of inherently chiral calixarenes with a highly distorted cavity potentially applicable to the design of new chiral receptors.",
author = "Petr Slav{\'i}k and Michal Kohout and Stanislav B{\"o}hm and V{\'a}clav Eigner and Pavel Lhot{\'a}k",
year = "2016",
month = feb,
day = "7",
doi = "10.1039/c5cc09388k",
language = "English",
volume = "52",
pages = "2366--2369",
journal = "Chemical communications",
issn = "1359-7345",
publisher = "The Royal Society of Chemistry",
number = "11",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Synthesis of inherently chiral calixarenes via direct mercuration of the partial cone conformation

AU - Slavík, Petr

AU - Kohout, Michal

AU - Böhm, Stanislav

AU - Eigner, Václav

AU - Lhoták, Pavel

PY - 2016/2/7

Y1 - 2016/2/7

N2 - Direct mercuration of calix[4]arene immobilized in the partial cone conformation led to the meta-substituted isomer which was subsequently subjected to Pd-catalysed coupling (C-H activation) with the neighbouring aromatic subunit. Regioselective mercuration thus enabled access to a novel type of inherently chiral calixarenes with a highly distorted cavity potentially applicable to the design of new chiral receptors.

AB - Direct mercuration of calix[4]arene immobilized in the partial cone conformation led to the meta-substituted isomer which was subsequently subjected to Pd-catalysed coupling (C-H activation) with the neighbouring aromatic subunit. Regioselective mercuration thus enabled access to a novel type of inherently chiral calixarenes with a highly distorted cavity potentially applicable to the design of new chiral receptors.

UR - http://www.scopus.com/inward/record.url?scp=84957827735&partnerID=8YFLogxK

U2 - 10.1039/c5cc09388k

DO - 10.1039/c5cc09388k

M3 - Article

AN - SCOPUS:84957827735

VL - 52

SP - 2366

EP - 2369

JO - Chemical communications

JF - Chemical communications

SN - 1359-7345

IS - 11

ER -