Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction

L G  Bonnet; R E  Douthwaite; B M  Kariuki

doi:10.1021/om034050z

Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction

L G Bonnet, R E Douthwaite, B M Kariuki

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Silver(I) and palladium(II) complexes of new chiral N-heterocyclic carbene (NHC)-imine ligands derived from trans-1,2-diaminocyclohexane have been prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction giving a maximum ee of 92%.

Original language	English
Pages (from-to)	4187-4189
Number of pages	3
Journal	Organometallics
Volume	22
Issue number	21
DOIs	https://doi.org/10.1021/om034050z
Publication status	Published - 13 Oct 2003

Keywords

METAL-COMPLEXES
CONJUGATE ADDITION
IMIDAZOLIUM SALTS
OLEFIN METATHESIS
CP-ASTERISK
PD COMPLEX
PALLADIUM
CATALYSIS
HYDROGENATION
ETA(5)-C5ME5

Access to Document

10.1021/om034050z

http://dx.doi.org/10.1021/om034050z

Cite this

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title = "Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction",

abstract = "Silver(I) and palladium(II) complexes of new chiral N-heterocyclic carbene (NHC)-imine ligands derived from trans-1,2-diaminocyclohexane have been prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction giving a maximum ee of 92%.",

keywords = "METAL-COMPLEXES, CONJUGATE ADDITION, IMIDAZOLIUM SALTS, OLEFIN METATHESIS, CP-ASTERISK, PD COMPLEX, PALLADIUM, CATALYSIS, HYDROGENATION, ETA(5)-C5ME5",

author = "Bonnet, {L G} and Douthwaite, {R E} and Kariuki, {B M}",

year = "2003",

month = oct,

day = "13",

doi = "10.1021/om034050z",

language = "English",

volume = "22",

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journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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T1 - Synthesis of new chiral N-heterocyclic carbene-imine ligands and their application to an asymmetric allylic alkylation reaction

AU - Bonnet, L G

AU - Douthwaite, R E

AU - Kariuki, B M

PY - 2003/10/13

Y1 - 2003/10/13

N2 - Silver(I) and palladium(II) complexes of new chiral N-heterocyclic carbene (NHC)-imine ligands derived from trans-1,2-diaminocyclohexane have been prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction giving a maximum ee of 92%.

AB - Silver(I) and palladium(II) complexes of new chiral N-heterocyclic carbene (NHC)-imine ligands derived from trans-1,2-diaminocyclohexane have been prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction giving a maximum ee of 92%.

KW - METAL-COMPLEXES

KW - CONJUGATE ADDITION

KW - IMIDAZOLIUM SALTS

KW - OLEFIN METATHESIS

KW - CP-ASTERISK

KW - PD COMPLEX

KW - PALLADIUM

KW - CATALYSIS

KW - HYDROGENATION

KW - ETA(5)-C5ME5

U2 - 10.1021/om034050z

DO - 10.1021/om034050z

M3 - Article

SN - 0276-7333

VL - 22

SP - 4187

EP - 4189

JO - Organometallics

JF - Organometallics

IS - 21

ER -