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Synthetic Approaches to Enantiomerically Enriched 4-Hydroxycyclohex-2-en-1-one - A Key Chiral Building Block in Complex Natural Product Synthesis

Research output: Contribution to journalLiterature review

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JournalSYNTHESIS-STUTTGART
DatePublished - Mar 2011
Issue number5
Number of pages27
Pages (from-to)681-707
Original languageEnglish

Abstract

4-Hydroxycyclohex-2-en-1-one and its derivatives have been used as the key chiral building blocks in a number of natural product and complex molecule syntheses. This review describes the many and varied methods for preparing the title compound in an enantioselective manner and also details how it has been utilised in natural product synthesis.

    Research areas

  • asymmetric catalysis, chiral auxiliaries, chiral pool, kinetic resolution, natural products, BACTERIAL-DNA PRIMASE, ALKYLIDENE-GAMMA-BUTYROLACTONES, ENANTIOSELECTIVE SYNTHESIS, STEREOSELECTIVE-SYNTHESIS, ABSOLUTE-CONFIGURATION, CONCISE SYNTHESIS, MICHAEL REACTION, BLENNOLIDE-C, EFFICIENT, INHIBITOR

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