Synthetic Studies towards the Africanane Sesquiterpenes via the Cope Rearrangement of gem -Dimethyl-Substituted Divinyl Cyclopropanes

Jonathan D. Osler; William P. Unsworth; Richard J K Taylor

doi:10.1055/s-0035-1560176

Synthetic Studies towards the Africanane Sesquiterpenes via the Cope Rearrangement of gem -Dimethyl-Substituted Divinyl Cyclopropanes

Jonathan D. Osler, William P. Unsworth^*, Richard J K Taylor

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The Cope rearrangement of gem-dimethyl-substituted divinylcyclopropanes has been used to construct functionalised cycloheptadienes. These scaffolds have been further elaborated to furnish advanced intermediates en route to africanane sesquiterpene natural products, most notably pyxidatol C.

Original language	English
Pages (from-to)	70-74
Number of pages	5
Journal	Synlett
Volume	27
Issue number	1
Early online date	24 Aug 2015
DOIs	https://doi.org/10.1055/s-0035-1560176
Publication status	Published - 4 Jan 2016

Bibliographical note

Keywords

africananes.
cyclopropanes
natural products
pericyclic reactions
pyxidatol C

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10.1055/s-0035-1560176

Taylor Pyxidatol C Synlett
© Georg Thieme Verlag. This is an author produced version of a paper published in Synlett. Uploaded in accordance with the publisher's self-archiving policy.
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Synthetic Studies towards the Africanane Sesquiterpenes via the Cope Rearrangement of gem -Dimethyl-Substituted Divinyl Cyclopropanes

Abstract

Bibliographical note

Keywords

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