Tandem oxidation processes: The direct conversion of activated alcohols into oximes; synthesis of citaldoxime

H Kanno, R J K Taylor

Research output: Contribution to journalArticlepeer-review

Abstract

The direct conversion of primary alcohols into oximes is reported using manganese dioxide and alkoxylamines/hydroxylamine as their hydrochloride salts or supported on Amberlyst 15. This transformation has been applied to a range of benzylic, allylic and proparaylic alcohols and utilised to prepare the natural product citaldoxime.

Original languageEnglish
Pages (from-to)1287-1290
Number of pages4
JournalSynlett
Issue number8
Publication statusPublished - Aug 2002

Keywords

  • oxidation
  • O-alkyl oximes
  • oximes
  • citaldoxime
  • one-pot
  • CITRUS

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