Tandem oxidation processes using manganese dioxide: Discovery, applications, and current studies

R J K  Taylor; M  Reid; J  Foot; S A  Raw

doi:10.1021/ar050113t

Tandem oxidation processes using manganese dioxide: Discovery, applications, and current studies

R J K Taylor, M Reid, J Foot, S A Raw

Chemistry

Research output: Contribution to journal › Literature review › peer-review

Abstract

"One-pot" processes in which alcohol oxidations are combined with further elaboration of the carbonyl intermediate are reviewed. Sequential processes are briefly discussed, but most attention is centered on tandem processes; that is, oxidations carried out in the presence of a nucleophilic trapping agent, rather than those in which the trapping agent is added after the oxidation is complete. As part of this Account, a comprehensive review of the discovery of tandem oxidation processes (TOP) will be given together with applications in alkene-forming reactions, cyclopropanations, and imine, oxime, amine, and heterocycle formation.

Original language	English
Pages (from-to)	851-869
Number of pages	19
Journal	ACCOUNTS OF CHEMICAL RESEARCH
Volume	38
Issue number	11
DOIs	https://doi.org/10.1021/ar050113t
Publication status	Published - Nov 2005

Keywords

CATALYZED AEROBIC OXIDATION
ONE-POT CONVERSION
ACTIVATED ALCOHOLS
WITTIG REACTIONS
CARBONYL-COMPOUNDS
ORGANIC-CHEMISTRY
PHOSPHORUS-YLIDE
CARBOXYLIC-ACIDS
ALDEHYDES
AMIDES

Access to Document

10.1021/ar050113t

Cite this

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title = "Tandem oxidation processes using manganese dioxide: Discovery, applications, and current studies",

abstract = "{"}One-pot{"} processes in which alcohol oxidations are combined with further elaboration of the carbonyl intermediate are reviewed. Sequential processes are briefly discussed, but most attention is centered on tandem processes; that is, oxidations carried out in the presence of a nucleophilic trapping agent, rather than those in which the trapping agent is added after the oxidation is complete. As part of this Account, a comprehensive review of the discovery of tandem oxidation processes (TOP) will be given together with applications in alkene-forming reactions, cyclopropanations, and imine, oxime, amine, and heterocycle formation.",

keywords = "CATALYZED AEROBIC OXIDATION, ONE-POT CONVERSION, ACTIVATED ALCOHOLS, WITTIG REACTIONS, CARBONYL-COMPOUNDS, ORGANIC-CHEMISTRY, PHOSPHORUS-YLIDE, CARBOXYLIC-ACIDS, ALDEHYDES, AMIDES",

author = "Taylor, {R J K} and M Reid and J Foot and Raw, {S A}",

year = "2005",

month = nov,

doi = "10.1021/ar050113t",

language = "English",

volume = "38",

pages = "851--869",

journal = "ACCOUNTS OF CHEMICAL RESEARCH",

issn = "0001-4842",

publisher = "American Chemical Society",

number = "11",

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TY - JOUR

T1 - Tandem oxidation processes using manganese dioxide: Discovery, applications, and current studies

AU - Taylor, R J K

AU - Reid, M

AU - Foot, J

AU - Raw, S A

PY - 2005/11

Y1 - 2005/11

N2 - "One-pot" processes in which alcohol oxidations are combined with further elaboration of the carbonyl intermediate are reviewed. Sequential processes are briefly discussed, but most attention is centered on tandem processes; that is, oxidations carried out in the presence of a nucleophilic trapping agent, rather than those in which the trapping agent is added after the oxidation is complete. As part of this Account, a comprehensive review of the discovery of tandem oxidation processes (TOP) will be given together with applications in alkene-forming reactions, cyclopropanations, and imine, oxime, amine, and heterocycle formation.

AB - "One-pot" processes in which alcohol oxidations are combined with further elaboration of the carbonyl intermediate are reviewed. Sequential processes are briefly discussed, but most attention is centered on tandem processes; that is, oxidations carried out in the presence of a nucleophilic trapping agent, rather than those in which the trapping agent is added after the oxidation is complete. As part of this Account, a comprehensive review of the discovery of tandem oxidation processes (TOP) will be given together with applications in alkene-forming reactions, cyclopropanations, and imine, oxime, amine, and heterocycle formation.

KW - CATALYZED AEROBIC OXIDATION

KW - ONE-POT CONVERSION

KW - ACTIVATED ALCOHOLS

KW - WITTIG REACTIONS

KW - CARBONYL-COMPOUNDS

KW - ORGANIC-CHEMISTRY

KW - PHOSPHORUS-YLIDE

KW - CARBOXYLIC-ACIDS

KW - ALDEHYDES

KW - AMIDES

U2 - 10.1021/ar050113t

DO - 10.1021/ar050113t

M3 - Literature review

SN - 0001-4842

VL - 38

SP - 851

EP - 869

JO - ACCOUNTS OF CHEMICAL RESEARCH

JF - ACCOUNTS OF CHEMICAL RESEARCH

IS - 11

ER -