The allylic oxidation of unsaturated steroids by tert-butyl hydroperoxide using surface functionalised silica supported metal catalysts

J A R Salvador, J H Clark

Research output: Contribution to journalArticlepeer-review

Abstract

Metal complexes based on Co(II), Cu(II), Mn(II) and V(II) immobilised on mesoporous silica, efficiently catalyse the selective allylic oxidation of unsaturated steroids and valencene, and can be easily recovered and reused.

Original languageEnglish
Pages (from-to)352-356
Number of pages5
JournalGreen Chemistry
Volume4
Issue number4
DOIs
Publication statusPublished - 2002

Keywords

  • STEREOSPECIFIC SYNTHESES
  • PYRIDINIUM DICHROMATE
  • CHOLESTERYL ACETATE
  • REAGENT
  • ALKENES
  • ENONES
  • CONVENIENT

Cite this