The antisymmetric stretching fundamental band of free MgD2

A  Shayesteh; D R T  Appadoo; I  Gordon; P F  Bernath

doi:10.1139/V04-043

The antisymmetric stretching fundamental band of free MgD2

A Shayesteh, D R T Appadoo, I Gordon, P F Bernath

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The gaseous MgD2 molecule has been synthesized for the first time in an electrical discharge inside a high-temperature furnace. The high-resolution infrared emission spectrum of MgD2 was recorded with a Fourier transform spectrometer, and the antisymmetric stretching mode (v(3)) was detected near 1176.5 cm(-1). The v(3) band was rotationally analyzed, and the r(0) Mg-D bond istance was determined to be 1.700 874(8) Angstrom.

Original language	English
Pages (from-to)	947-950
Number of pages	4
Journal	CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
Volume	82
Issue number	6
DOIs	https://doi.org/10.1139/V04-043
Publication status	Published - Jun 2004

Keywords

gaseous MgD2
vibration-rotation emission spectrum
Mg-D bond distance
MAGNESIUM HYDRIDE
MOLECULES
MGH2
SPECTRA
ATOM

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10.1139/V04-043

Cite this

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title = "The antisymmetric stretching fundamental band of free MgD2",

abstract = "The gaseous MgD2 molecule has been synthesized for the first time in an electrical discharge inside a high-temperature furnace. The high-resolution infrared emission spectrum of MgD2 was recorded with a Fourier transform spectrometer, and the antisymmetric stretching mode (v(3)) was detected near 1176.5 cm(-1). The v(3) band was rotationally analyzed, and the r(0) Mg-D bond istance was determined to be 1.700 874(8) Angstrom.",

keywords = "gaseous MgD2, vibration-rotation emission spectrum, Mg-D bond distance, MAGNESIUM HYDRIDE, MOLECULES, MGH2, SPECTRA, ATOM",

author = "A Shayesteh and Appadoo, {D R T} and I Gordon and Bernath, {P F}",

year = "2004",

month = jun,

doi = "10.1139/V04-043",

language = "English",

volume = "82",

pages = "947--950",

journal = "CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE",

issn = "0008-4042",

publisher = "National Research Council of Canada",

number = "6",

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TY - JOUR

T1 - The antisymmetric stretching fundamental band of free MgD2

AU - Shayesteh, A

AU - Appadoo, D R T

AU - Gordon, I

AU - Bernath, P F

PY - 2004/6

Y1 - 2004/6

N2 - The gaseous MgD2 molecule has been synthesized for the first time in an electrical discharge inside a high-temperature furnace. The high-resolution infrared emission spectrum of MgD2 was recorded with a Fourier transform spectrometer, and the antisymmetric stretching mode (v(3)) was detected near 1176.5 cm(-1). The v(3) band was rotationally analyzed, and the r(0) Mg-D bond istance was determined to be 1.700 874(8) Angstrom.

AB - The gaseous MgD2 molecule has been synthesized for the first time in an electrical discharge inside a high-temperature furnace. The high-resolution infrared emission spectrum of MgD2 was recorded with a Fourier transform spectrometer, and the antisymmetric stretching mode (v(3)) was detected near 1176.5 cm(-1). The v(3) band was rotationally analyzed, and the r(0) Mg-D bond istance was determined to be 1.700 874(8) Angstrom.

KW - gaseous MgD2

KW - vibration-rotation emission spectrum

KW - Mg-D bond distance

KW - MAGNESIUM HYDRIDE

KW - MOLECULES

KW - MGH2

KW - SPECTRA

KW - ATOM

U2 - 10.1139/V04-043

DO - 10.1139/V04-043

M3 - Article

SN - 0008-4042

VL - 82

SP - 947

EP - 950

JO - CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE

JF - CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE

IS - 6

ER -