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The antisymmetric stretching fundamental band of free MgD2

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JournalCANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
DatePublished - Jun 2004
Issue number6
Volume82
Number of pages4
Pages (from-to)947-950
Original languageEnglish

Abstract

The gaseous MgD2 molecule has been synthesized for the first time in an electrical discharge inside a high-temperature furnace. The high-resolution infrared emission spectrum of MgD2 was recorded with a Fourier transform spectrometer, and the antisymmetric stretching mode (v(3)) was detected near 1176.5 cm(-1). The v(3) band was rotationally analyzed, and the r(0) Mg-D bond istance was determined to be 1.700 874(8) Angstrom.

    Research areas

  • gaseous MgD2, vibration-rotation emission spectrum, Mg-D bond distance, MAGNESIUM HYDRIDE, MOLECULES, MGH2, SPECTRA, ATOM

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