Abstract
Caged peroxide: An octanuclear nickel complex, which exhibits peroxide in an unprecedented 6-(1)3 coordination mode, was prepared (see structure: only the Ni8 unit with the central peroxo ligand and the bridging oxygen atoms is shown; green Ni, red O). This mode of binding finally completes the series of symmetrical n-(1)n/2 peroxide binding modes in complexes.
Original language | English |
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Pages (from-to) | 1392-1395 |
Number of pages | 4 |
Journal | Angewandte Chemie International Edition |
Volume | 44 |
Issue number | 9 |
DOIs | |
Publication status | Published - 3 Jan 2005 |
Keywords
- cluster compounds
- coordination modes
- hydroxypyridinones
- nickel
- peroxides
- NICKEL(I) COMPLEX
- DIOXYGEN
- INTERMEDIATE
- PEROXIDE
- LIGAND
- OXYGENATION
- REACTIVITY
- RELEVANCE
- OXIDATION
- CLUSTER