The in situ oxidation-Wittig reaction of alpha-hydroxyketones

K A  Runcie; R J K  Taylor

doi:10.1039/b201513g

The in situ oxidation-Wittig reaction of alpha-hydroxyketones

K A Runcie, R J K Taylor

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In situ oxidation-Wittig methodology has been applied to a alpha-hydroxyketones avoiding the problems normally associated with alpha-ketoaldehydes; the procedure is practically simple, and in many cases gives high yields of the product gamma-ketocrotonates; the procedure has also been successfully utilised with ethyl glycolate and glycolaldehyde dimer.

Original language	English
Pages (from-to)	974-975
Number of pages	2
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/b201513g
Publication status	Published - 2002

Keywords

ALCOHOLS

Access to Document

10.1039/b201513g

Cite this

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abstract = "In situ oxidation-Wittig methodology has been applied to a alpha-hydroxyketones avoiding the problems normally associated with alpha-ketoaldehydes; the procedure is practically simple, and in many cases gives high yields of the product gamma-ketocrotonates; the procedure has also been successfully utilised with ethyl glycolate and glycolaldehyde dimer.",

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AB - In situ oxidation-Wittig methodology has been applied to a alpha-hydroxyketones avoiding the problems normally associated with alpha-ketoaldehydes; the procedure is practically simple, and in many cases gives high yields of the product gamma-ketocrotonates; the procedure has also been successfully utilised with ethyl glycolate and glycolaldehyde dimer.

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