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The introduction of SCF3 into aromatic substrates using CuSCF3 and alumina-supported CuSCF3

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Published copy (DOI)

Author(s)

  • James H. Clark
  • Craig W. Jones
  • Adrian P. Kybett
  • Martin A. McClinton
  • Jack M. Miller
  • David Bishop
  • Robert J. Blade

Department/unit(s)

Publication details

JournalJOURNAL OF FLUORINE CHEMISTRY
DatePublished - 15 Jun 1990
Issue number2
Volume48
Number of pages5
Pages (from-to)249-253
Original languageEnglish

Abstract

Trifluoromethylthiocopper(I) has been readily prepared from the silver analogue, using a metathetical reaction with copper(I) bromide. Homogeneous CuSCF3 and the supported reagent CuSCF3-alumina have been compared in their reactivity towards aryl iodides, in order to form trifluoromethylaryl sulphides in good yields.

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