The near infrared, visible, and near ultraviolet overtone spectrum of water

M  Carleer; A  Jenouvrier; A C  Vandaele; P F  Bernath; M F  Merienne; R  Colin; N F  Zobov; O L  Polyansky; J  Tennyson; V A  Savin

The near infrared, visible, and near ultraviolet overtone spectrum of water

M Carleer, A Jenouvrier, A C Vandaele, P F Bernath, M F Merienne, R Colin, N F Zobov, O L Polyansky, J Tennyson, V A Savin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

New long path length, high resolution, Fourier transform spectrometer measurements for water are presented. These spectra cover the near infrared, visible, and near ultraviolet regions and contain water transitions belonging to all polyads from 3 nu to 8 nu. Transitions in the range 13 100-21 400 cm(-1) are analyzed using line lists computed using variational first-principles calculations. 2286 new transitions are assigned to (H2O)-O-16. These result in the observation of transitions in 15 new overtone and combination bands of water. Energy levels for these and other newly observed levels are presented. It is suggested that local mode rather than normal mode vibrational assignments are more appropriate for the vibrational states of water in polyads 4 nu and above. (C) 1999 American Institute of Physics. [S0021-9606(99)00830-2].

Original language	English
Pages (from-to)	2444-2450
Number of pages	7
Journal	Journal of Chemical Physics
Volume	111
Issue number	6
Publication status	Published - 8 Aug 1999

Keywords

HIGH-RESOLUTION SPECTRUM
LINE ASSIGNMENTS
12750 CM(-1)
VAPOR
SPECTROSCOPY
CM-1
INTENSITIES
ABSORPTION
POSITIONS
H2O

Cite this

@article{9991022540504b558a311e2cabed5111,

title = "The near infrared, visible, and near ultraviolet overtone spectrum of water",

abstract = "New long path length, high resolution, Fourier transform spectrometer measurements for water are presented. These spectra cover the near infrared, visible, and near ultraviolet regions and contain water transitions belonging to all polyads from 3 nu to 8 nu. Transitions in the range 13 100-21 400 cm(-1) are analyzed using line lists computed using variational first-principles calculations. 2286 new transitions are assigned to (H2O)-O-16. These result in the observation of transitions in 15 new overtone and combination bands of water. Energy levels for these and other newly observed levels are presented. It is suggested that local mode rather than normal mode vibrational assignments are more appropriate for the vibrational states of water in polyads 4 nu and above. (C) 1999 American Institute of Physics. [S0021-9606(99)00830-2].",

keywords = "HIGH-RESOLUTION SPECTRUM, LINE ASSIGNMENTS, 12750 CM(-1), VAPOR, SPECTROSCOPY, CM-1, INTENSITIES, ABSORPTION, POSITIONS, H2O",

author = "M Carleer and A Jenouvrier and Vandaele, {A C} and Bernath, {P F} and Merienne, {M F} and R Colin and Zobov, {N F} and Polyansky, {O L} and J Tennyson and Savin, {V A}",

year = "1999",

month = aug,

day = "8",

language = "English",

volume = "111",

pages = "2444--2450",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "6",

}

TY - JOUR

T1 - The near infrared, visible, and near ultraviolet overtone spectrum of water

AU - Carleer, M

AU - Jenouvrier, A

AU - Vandaele, A C

AU - Bernath, P F

AU - Merienne, M F

AU - Colin, R

AU - Zobov, N F

AU - Polyansky, O L

AU - Tennyson, J

AU - Savin, V A

PY - 1999/8/8

Y1 - 1999/8/8

N2 - New long path length, high resolution, Fourier transform spectrometer measurements for water are presented. These spectra cover the near infrared, visible, and near ultraviolet regions and contain water transitions belonging to all polyads from 3 nu to 8 nu. Transitions in the range 13 100-21 400 cm(-1) are analyzed using line lists computed using variational first-principles calculations. 2286 new transitions are assigned to (H2O)-O-16. These result in the observation of transitions in 15 new overtone and combination bands of water. Energy levels for these and other newly observed levels are presented. It is suggested that local mode rather than normal mode vibrational assignments are more appropriate for the vibrational states of water in polyads 4 nu and above. (C) 1999 American Institute of Physics. [S0021-9606(99)00830-2].

AB - New long path length, high resolution, Fourier transform spectrometer measurements for water are presented. These spectra cover the near infrared, visible, and near ultraviolet regions and contain water transitions belonging to all polyads from 3 nu to 8 nu. Transitions in the range 13 100-21 400 cm(-1) are analyzed using line lists computed using variational first-principles calculations. 2286 new transitions are assigned to (H2O)-O-16. These result in the observation of transitions in 15 new overtone and combination bands of water. Energy levels for these and other newly observed levels are presented. It is suggested that local mode rather than normal mode vibrational assignments are more appropriate for the vibrational states of water in polyads 4 nu and above. (C) 1999 American Institute of Physics. [S0021-9606(99)00830-2].

KW - HIGH-RESOLUTION SPECTRUM

KW - LINE ASSIGNMENTS

KW - 12750 CM(-1)

KW - VAPOR

KW - SPECTROSCOPY

KW - CM-1

KW - INTENSITIES

KW - ABSORPTION

KW - POSITIONS

KW - H2O

M3 - Article

SN - 0021-9606

VL - 111

SP - 2444

EP - 2450

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 6

ER -