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The preparation of trifluoromethyl aryl sulfides using KF and thiophosgene

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JournalJOURNAL OF FLUORINE CHEMISTRY
DatePublished - 1 Oct 1997
Issue number2
Volume85
Number of pages4
Pages (from-to)169-172
Original languageEnglish

Abstract

The trifluoromethanethiolate anion may be generated in situ by the reaction of thiophosgene with potassium fluoride in acetonitrile. This system is used to prepare trifluoromethyl aryl sulfides from activated fluoro-and chloroaromatic substrates via nucleophilic substitution. (C) 1997 Elsevier Science S.A.

    Research areas

  • trifluoromethyl aryl sulphides, fluoride, trifluoromethanethiolate anion

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