The spin-coupled picture of clamped benzenes

J G  Hill; P B  Karadakov; D L  Cooper

doi:10.1080/0028970500417630

The spin-coupled picture of clamped benzenes

J G Hill, P B Karadakov, D L Cooper

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Spin-coupled investigations into the clamped benzenes tris(bicyclo[2.1.1] hexano) benzene and tris(benzocyclobutadieno) benzene probe the effects of clamping groups by distinguishing between a central aromatic benzene moiety and localized p bonding in central 1,3, 5-cyclohexatriene-like rings, in terms of resonance between spin functions, orbital snapshot diagrams, and orbital overlap integrals.

Original language	English
Pages (from-to)	677-680
Number of pages	4
Journal	Journal of Physics B: Atomic, Molecular and Optical Physics
Volume	104
Issue number	5-7
DOIs	https://doi.org/10.1080/0028970500417630
Publication status	Published - 2006

Keywords

clamped benzenes
spin-coupled picture
VALENCE-BOND THEORY
CHEMICAL-SHIFTS
RING CURRENTS
AROMATICITY

Access to Document

10.1080/0028970500417630

Cite this

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title = "The spin-coupled picture of clamped benzenes",

abstract = "Spin-coupled investigations into the clamped benzenes tris(bicyclo[2.1.1] hexano) benzene and tris(benzocyclobutadieno) benzene probe the effects of clamping groups by distinguishing between a central aromatic benzene moiety and localized p bonding in central 1,3, 5-cyclohexatriene-like rings, in terms of resonance between spin functions, orbital snapshot diagrams, and orbital overlap integrals.",

keywords = "clamped benzenes, spin-coupled picture, VALENCE-BOND THEORY, CHEMICAL-SHIFTS, RING CURRENTS, AROMATICITY",

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journal = "Journal of Physics B: Atomic, Molecular and Optical Physics",

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AU - Cooper, D L

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AB - Spin-coupled investigations into the clamped benzenes tris(bicyclo[2.1.1] hexano) benzene and tris(benzocyclobutadieno) benzene probe the effects of clamping groups by distinguishing between a central aromatic benzene moiety and localized p bonding in central 1,3, 5-cyclohexatriene-like rings, in terms of resonance between spin functions, orbital snapshot diagrams, and orbital overlap integrals.

KW - clamped benzenes

KW - spin-coupled picture

KW - VALENCE-BOND THEORY

KW - CHEMICAL-SHIFTS

KW - RING CURRENTS

KW - AROMATICITY

U2 - 10.1080/0028970500417630

DO - 10.1080/0028970500417630

M3 - Article

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JO - Journal of Physics B: Atomic, Molecular and Optical Physics

JF - Journal of Physics B: Atomic, Molecular and Optical Physics

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