The study of inorganic systems by NMR spectroscopy in conjunction with parahydrogen-induced polarisation

S B  Duckett; D  Blazina

doi:10.1002/ejic.200300119

The study of inorganic systems by NMR spectroscopy in conjunction with parahydrogen-induced polarisation

S B Duckett, D Blazina

Chemistry

Research output: Contribution to journal › Literature review › peer-review

Abstract

The study of reaction mechanisms by NMR spectroscopy normally suffers from limitations in sensitivity that result in substantial difficulties in the detection and characterisation of reaction intermediates. One technique that can circumvent this problem is the use of para-enriched hydrogen. Here, an overview of the developments in the study of chemical reactions using parahydrogen-assisted NMR spectroscopy is presented, with the characterisation of a number of new hydride complexes of iridium, rhodium, ruthenium and tantalum being described. A number of studies involving transition metal clusters and catalytic applications are also considered. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

Original language	English
Pages (from-to)	2901-2912
Number of pages	12
Journal	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Issue number	16
DOIs	https://doi.org/10.1002/ejic.200300119
Publication status	Published - 18 Aug 2003

Keywords

NMR spectroscopy
parahydrogen
iridium
rhodium
ruthenium
HYDROGEN INDUCED POLARIZATION
NUCLEAR-MAGNETIC-RESONANCE
DETECT SPECIES PRESENT
IN-SITU
HOMOGENEOUS HYDROGENATION
DIHYDRIDE COMPLEXES
OXIDATIVE ADDITION
PHIP-NMR
TANTALOCENE COMPLEXES
DIHYDROGEN ADDITION

Access to Document

10.1002/ejic.200300119

Cite this

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title = "The study of inorganic systems by NMR spectroscopy in conjunction with parahydrogen-induced polarisation",

abstract = "The study of reaction mechanisms by NMR spectroscopy normally suffers from limitations in sensitivity that result in substantial difficulties in the detection and characterisation of reaction intermediates. One technique that can circumvent this problem is the use of para-enriched hydrogen. Here, an overview of the developments in the study of chemical reactions using parahydrogen-assisted NMR spectroscopy is presented, with the characterisation of a number of new hydride complexes of iridium, rhodium, ruthenium and tantalum being described. A number of studies involving transition metal clusters and catalytic applications are also considered. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.",

keywords = "NMR spectroscopy, parahydrogen, iridium, rhodium, ruthenium, HYDROGEN INDUCED POLARIZATION, NUCLEAR-MAGNETIC-RESONANCE, DETECT SPECIES PRESENT, IN-SITU, HOMOGENEOUS HYDROGENATION, DIHYDRIDE COMPLEXES, OXIDATIVE ADDITION, PHIP-NMR, TANTALOCENE COMPLEXES, DIHYDROGEN ADDITION",

author = "Duckett, {S B} and D Blazina",

year = "2003",

month = aug,

day = "18",

doi = "10.1002/ejic.200300119",

language = "English",

pages = "2901--2912",

journal = "EUROPEAN JOURNAL OF INORGANIC CHEMISTRY",

issn = "1434-1948",

publisher = "Wiley-Blackwell",

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TY - JOUR

T1 - The study of inorganic systems by NMR spectroscopy in conjunction with parahydrogen-induced polarisation

AU - Duckett, S B

AU - Blazina, D

PY - 2003/8/18

Y1 - 2003/8/18

N2 - The study of reaction mechanisms by NMR spectroscopy normally suffers from limitations in sensitivity that result in substantial difficulties in the detection and characterisation of reaction intermediates. One technique that can circumvent this problem is the use of para-enriched hydrogen. Here, an overview of the developments in the study of chemical reactions using parahydrogen-assisted NMR spectroscopy is presented, with the characterisation of a number of new hydride complexes of iridium, rhodium, ruthenium and tantalum being described. A number of studies involving transition metal clusters and catalytic applications are also considered. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

AB - The study of reaction mechanisms by NMR spectroscopy normally suffers from limitations in sensitivity that result in substantial difficulties in the detection and characterisation of reaction intermediates. One technique that can circumvent this problem is the use of para-enriched hydrogen. Here, an overview of the developments in the study of chemical reactions using parahydrogen-assisted NMR spectroscopy is presented, with the characterisation of a number of new hydride complexes of iridium, rhodium, ruthenium and tantalum being described. A number of studies involving transition metal clusters and catalytic applications are also considered. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

KW - NMR spectroscopy

KW - parahydrogen

KW - iridium

KW - rhodium

KW - ruthenium

KW - HYDROGEN INDUCED POLARIZATION

KW - NUCLEAR-MAGNETIC-RESONANCE

KW - DETECT SPECIES PRESENT

KW - IN-SITU

KW - HOMOGENEOUS HYDROGENATION

KW - DIHYDRIDE COMPLEXES

KW - OXIDATIVE ADDITION

KW - PHIP-NMR

KW - TANTALOCENE COMPLEXES

KW - DIHYDROGEN ADDITION

U2 - 10.1002/ejic.200300119

DO - 10.1002/ejic.200300119

M3 - Literature review

SN - 1434-1948

SP - 2901

EP - 2912

JO - EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

JF - EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

IS - 16

ER -