By the same authors

From the same journal

The study of inorganic systems by NMR spectroscopy in conjunction with parahydrogen-induced polarisation

Research output: Contribution to journalLiterature review

Published copy (DOI)

Author(s)

Department/unit(s)

Publication details

JournalEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
DatePublished - 18 Aug 2003
Issue number16
Number of pages12
Pages (from-to)2901-2912
Original languageEnglish

Abstract

The study of reaction mechanisms by NMR spectroscopy normally suffers from limitations in sensitivity that result in substantial difficulties in the detection and characterisation of reaction intermediates. One technique that can circumvent this problem is the use of para-enriched hydrogen. Here, an overview of the developments in the study of chemical reactions using parahydrogen-assisted NMR spectroscopy is presented, with the characterisation of a number of new hydride complexes of iridium, rhodium, ruthenium and tantalum being described. A number of studies involving transition metal clusters and catalytic applications are also considered. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

    Research areas

  • NMR spectroscopy, parahydrogen, iridium, rhodium, ruthenium, HYDROGEN INDUCED POLARIZATION, NUCLEAR-MAGNETIC-RESONANCE, DETECT SPECIES PRESENT, IN-SITU, HOMOGENEOUS HYDROGENATION, DIHYDRIDE COMPLEXES, OXIDATIVE ADDITION, PHIP-NMR, TANTALOCENE COMPLEXES, DIHYDROGEN ADDITION

Discover related content

Find related publications, people, projects, datasets and more using interactive charts.

View graph of relations