THE SYNTHESIS AND MESOMORPHISM OF A NEW SERIES OF SILVER(I) COMPLEXES SHOWING GLASSY MESOPHASES

D W BRUCE, B DONNIO, D GUILLON, B HEINRICH, M IBNELHAJ

Research output: Contribution to journalComment/debatepeer-review

Abstract

Reaction of 3,4-dialkoxystilbazoles (n-3,4-OPhVPy) with silver dodecylsulphate (AgDOS) leads to complexes of the formula [Ag(n-3,4-OPhVPy)(2)][DOS]. These complexes are polycatenar liquid crystals and show mesophases which are characteristic of this structural type, namely, hexagonal, columnar and cubic. On cooling, some of the materials do not crystallize, but form stable glasses instead. All the mesophases have been fully characterized by small angle X-ray diffraction.

Original languageEnglish
Pages (from-to)537-539
Number of pages3
JournalLIQUID CRYSTALS
Volume19
Issue number4
Publication statusPublished - Oct 1995

Keywords

  • LIQUID-CRYSTALLINE

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