The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(II)

R E  Douthwaite; J  Houghton; B M  Kariuki

doi:10.1039/b314814a

The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(II)

R E Douthwaite, J Houghton, B M Kariuki

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A diimidazolium salt incorporating a secondary amine moiety has been used to prepare a palladium(II) di-N-heterocyclic carbene amino complex that can be deprotonated with NaH to give the first example of a transition metal NHC-amide.

Original language	English
Pages (from-to)	698-699
Number of pages	2
Journal	Chemical Communications
Volume	20
Issue number	6
DOIs	https://doi.org/10.1039/b314814a
Publication status	Published - 21 Mar 2004

Keywords

LIGANDS
COPOLYMERIZATION
DINITROGEN
CATALYSIS
MONOXIDE
COPPER
SILVER

Access to Document

10.1039/b314814a

http://dx.doi.org/10.1039/b314814a

Cite this

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title = "The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(II)",

abstract = "A diimidazolium salt incorporating a secondary amine moiety has been used to prepare a palladium(II) di-N-heterocyclic carbene amino complex that can be deprotonated with NaH to give the first example of a transition metal NHC-amide.",

keywords = "LIGANDS, COPOLYMERIZATION, DINITROGEN, CATALYSIS, MONOXIDE, COPPER, SILVER",

author = "Douthwaite, {R E} and J Houghton and Kariuki, {B M}",

year = "2004",

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AU - Houghton, J

AU - Kariuki, B M

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N2 - A diimidazolium salt incorporating a secondary amine moiety has been used to prepare a palladium(II) di-N-heterocyclic carbene amino complex that can be deprotonated with NaH to give the first example of a transition metal NHC-amide.

AB - A diimidazolium salt incorporating a secondary amine moiety has been used to prepare a palladium(II) di-N-heterocyclic carbene amino complex that can be deprotonated with NaH to give the first example of a transition metal NHC-amide.

KW - LIGANDS

KW - COPOLYMERIZATION

KW - DINITROGEN

KW - CATALYSIS

KW - MONOXIDE

KW - COPPER

KW - SILVER

U2 - 10.1039/b314814a

DO - 10.1039/b314814a

M3 - Article

SN - 1359-7345

VL - 20

SP - 698

EP - 699

JO - Chemical Communications

JF - Chemical Communications

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