The vibration-rotation emission spectrum of gaseous HZnCl

S S  Yu; A  Shayesteh; D J  Fu; P F  Bernath

doi:10.1021/jp0509010

The vibration-rotation emission spectrum of gaseous HZnCl

S S Yu, A Shayesteh, D J Fu, P F Bernath

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Gaseous HZnCl has been synthesized for the first time in a high-temperature tube furnace with a dc discharge in a flowing mixture of pure HCl and Zn vapor. The vibration-rotation emission spectrum of HZnCl was recorded at high resolution using a Fourier transform spectrometer. The H-Zn stretching modes (v(1)) of the (HZnCl)-Zn-64-Cl-35, (HZnCl)-Zn-66-Cl-35, (HZnCl)-Zn-68-Cl-35, and (HZnCl)-Zn-64-Cl-37 species, as well as the 2v(1)-v(1) hot band of the most abundant isotopologue (HZnCl)-Zn-64-Cl-35, were observed near 1966 cm(-1). A least-squares fit was performed for each of the four observed isotopologues, and their spectroscopic constants were determined.

Original language	English
Pages (from-to)	4092-4094
Number of pages	3
Journal	Journal of Physical Chemistry A
Volume	109
Issue number	18
DOIs	https://doi.org/10.1021/jp0509010
Publication status	Published - 12 May 2005

Keywords

ELECTRON-SPIN-RESONANCE
MATRIX-ISOLATION ESR
ATOMS
ZNH2
HG

Access to Document

10.1021/jp0509010

Cite this

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title = "The vibration-rotation emission spectrum of gaseous HZnCl",

abstract = "Gaseous HZnCl has been synthesized for the first time in a high-temperature tube furnace with a dc discharge in a flowing mixture of pure HCl and Zn vapor. The vibration-rotation emission spectrum of HZnCl was recorded at high resolution using a Fourier transform spectrometer. The H-Zn stretching modes (v(1)) of the (HZnCl)-Zn-64-Cl-35, (HZnCl)-Zn-66-Cl-35, (HZnCl)-Zn-68-Cl-35, and (HZnCl)-Zn-64-Cl-37 species, as well as the 2v(1)-v(1) hot band of the most abundant isotopologue (HZnCl)-Zn-64-Cl-35, were observed near 1966 cm(-1). A least-squares fit was performed for each of the four observed isotopologues, and their spectroscopic constants were determined.",

keywords = "ELECTRON-SPIN-RESONANCE, MATRIX-ISOLATION ESR, ATOMS, ZNH2, HG",

author = "Yu, {S S} and A Shayesteh and Fu, {D J} and Bernath, {P F}",

year = "2005",

month = may,

day = "12",

doi = "10.1021/jp0509010",

language = "English",

volume = "109",

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journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

publisher = "American Chemical Society",

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TY - JOUR

T1 - The vibration-rotation emission spectrum of gaseous HZnCl

AU - Yu, S S

AU - Shayesteh, A

AU - Fu, D J

AU - Bernath, P F

PY - 2005/5/12

Y1 - 2005/5/12

N2 - Gaseous HZnCl has been synthesized for the first time in a high-temperature tube furnace with a dc discharge in a flowing mixture of pure HCl and Zn vapor. The vibration-rotation emission spectrum of HZnCl was recorded at high resolution using a Fourier transform spectrometer. The H-Zn stretching modes (v(1)) of the (HZnCl)-Zn-64-Cl-35, (HZnCl)-Zn-66-Cl-35, (HZnCl)-Zn-68-Cl-35, and (HZnCl)-Zn-64-Cl-37 species, as well as the 2v(1)-v(1) hot band of the most abundant isotopologue (HZnCl)-Zn-64-Cl-35, were observed near 1966 cm(-1). A least-squares fit was performed for each of the four observed isotopologues, and their spectroscopic constants were determined.

AB - Gaseous HZnCl has been synthesized for the first time in a high-temperature tube furnace with a dc discharge in a flowing mixture of pure HCl and Zn vapor. The vibration-rotation emission spectrum of HZnCl was recorded at high resolution using a Fourier transform spectrometer. The H-Zn stretching modes (v(1)) of the (HZnCl)-Zn-64-Cl-35, (HZnCl)-Zn-66-Cl-35, (HZnCl)-Zn-68-Cl-35, and (HZnCl)-Zn-64-Cl-37 species, as well as the 2v(1)-v(1) hot band of the most abundant isotopologue (HZnCl)-Zn-64-Cl-35, were observed near 1966 cm(-1). A least-squares fit was performed for each of the four observed isotopologues, and their spectroscopic constants were determined.

KW - ELECTRON-SPIN-RESONANCE

KW - MATRIX-ISOLATION ESR

KW - ATOMS

KW - ZNH2

KW - HG

U2 - 10.1021/jp0509010

DO - 10.1021/jp0509010

M3 - Article

SN - 1089-5639

VL - 109

SP - 4092

EP - 4094

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 18

ER -