The visible and near ultraviolet rotation-vibration spectrum of HOD

A Jenouvrier, M F Merienne, M Carleer, R Colin, A C Vandaele, P F Bernath, O L Polyansky, J Tennyson

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Abstract

A Fourier transform spectrum has been recorded of a H2O/D2O vapor mixture in the wavenumber range 16,300 to 22,800 cm(-1) using a long path cell. 410 lines of HDO are assigned to the OH stretching overtone bands 5 nu (3). 6 nu (3) and 7 nu (3) plus combination bands. Assignments for the 6 nu (3) and 7 nu (3) bands represent the first data for the 006 and 007 states and give band origins of 19.836.88 cm(-1) and 22,625.50 cm(-1), respectively. Rotational term values for these states are also obtained. (C) 2001 Academic Press.

Original languageEnglish
Pages (from-to)165-168
Number of pages4
JournalJOURNAL OF MOLECULAR SPECTROSCOPY
Volume209
Issue number2
DOIs
Publication statusPublished - Oct 2001

Keywords

  • ABSORPTION-SPECTRUM
  • AB-INITIO
  • HDO
  • WATER
  • SPECTROSCOPY
  • OVERTONE
  • REGION

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