Abstract
The thermal expansion of a synthetic single-crystal sample of magnetite (Fe3O4) in the [111] direction has been investigated for the temperature range of 4.2-300 K using three-terminal capacitance dilatometry. The strain results and corresponding thermal expansion curve show the Verwey transition to be first-order with T-v 120 = 2 K. At T 4.2-70 K, the sample shows Invar-like behaviour.
Original language | English |
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Pages (from-to) | 1913-1921 |
Number of pages | 9 |
Journal | Philosophical Magazine |
Volume | 89 |
Issue number | 22-24 |
DOIs | |
Publication status | Published - Jan 2009 |
Keywords
- magnetite
- Verwey transition
- three-terminal capacitance dilatometry
- thermal expansion
- VERWEY TRANSITION
- LOW-TEMPERATURES
- FE3O4
- OXIDES