Thiosulfonates as Emerging Reactants: Synthesis and Applications

TY - JOUR

T1 - Thiosulfonates as Emerging Reactants

T2 - Synthesis and Applications

AU - Mampuys, P.

AU - McElroy, C. R.

AU - Clark, J. H.

AU - Orru, R. V.A.

AU - Maes, B. U.W.

N1 - © 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

PY - 2019/12/18

Y1 - 2019/12/18

N2 - The synthetic strategies towards thiosulfonates (RSO2SR1) are comprehensively reviewed from their original discovery to recent advances. Incorporation of the green credentials of the synthetic procedures towards thiosulfonates allows one to judge the merits of the state of the art, beyond the typical yield of a product and availability of the reactants. As reactant for organic transformations, thiosulfonates are particularly interesting given their possibility to react with nucleophiles, electrophiles and radicals. This review aims to give researchers, not familiar with the field, a good understanding of the general applications of thiosulfonates, while not skipping the recent important advances. The related, but less explored, selenosulfonates (RSO2SeR1) are also covered. (Figure presented.).

AB - The synthetic strategies towards thiosulfonates (RSO2SR1) are comprehensively reviewed from their original discovery to recent advances. Incorporation of the green credentials of the synthetic procedures towards thiosulfonates allows one to judge the merits of the state of the art, beyond the typical yield of a product and availability of the reactants. As reactant for organic transformations, thiosulfonates are particularly interesting given their possibility to react with nucleophiles, electrophiles and radicals. This review aims to give researchers, not familiar with the field, a good understanding of the general applications of thiosulfonates, while not skipping the recent important advances. The related, but less explored, selenosulfonates (RSO2SeR1) are also covered. (Figure presented.).

KW - green chemistry

KW - multicomponent reactions

KW - sulfur

KW - synthetic applications

KW - thiosulfonates

UR - http://www.scopus.com/inward/record.url?scp=85077018791&partnerID=8YFLogxK

U2 - 10.1002/adsc.201900864

DO - 10.1002/adsc.201900864

M3 - Review article

AN - SCOPUS:85077018791

SN - 1615-4150

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

ER -