Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

Alexander J Bukvic; Dana Georgiana Crivoi; Hollie G Garwood; Alasdair I McKay; Thomas T D Chen; Antonio J Martínez-Martínez; Andrew S Weller

doi:10.1039/d0cc01140a

Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

Alexander J Bukvic, Dana Georgiana Crivoi, Hollie G Garwood, Alasdair I McKay, Thomas T D Chen, Antonio J Martínez-Martínez, Andrew S Weller

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BArF4]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.

Original language	English
Article number	D0CC01140A
Journal	Chemical communications
Early online date	19 Mar 2020
DOIs	https://doi.org/10.1039/d0cc01140a
Publication status	E-pub ahead of print - 19 Mar 2020

Bibliographical note

This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

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10.1039/d0cc01140aLicence: CC BY

d0cc01140a
© The Royal Society of Chemistry 2020.
Final published version, 3.47 MBLicence: CC BY

Putting Low Coordination into Practice by the Exploration of Metal-sigma-Interactions: Fundamentals, New Catalysts and Catalysis for New Materials
Weller, A. (Principal investigator)
EPSRC
1/01/20 → 31/03/22
Project: Research project (funded) › Research
The Coordination Chemistry of Light Alkanes
Weller, A. (Principal investigator)
1/10/15 → 30/06/20
Project: Research project (funded) › Research

Cite this

Bukvic, A. J., Crivoi, D. G., Garwood, H. G., McKay, A. I., Chen, T. T. D., Martínez-Martínez, A. J., & Weller, A. S. (2020). Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer. Chemical communications, Article D0CC01140A. Advance online publication. https://doi.org/10.1039/d0cc01140a

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abstract = "Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BArF4]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.",

author = "Bukvic, {Alexander J} and Crivoi, {Dana Georgiana} and Garwood, {Hollie G} and McKay, {Alasdair I} and Chen, {Thomas T D} and Mart{\'i}nez-Mart{\'i}nez, {Antonio J} and Weller, {Andrew S}",

note = "This is an author-produced version of the published paper. Uploaded in accordance with the publisher{\textquoteright}s self-archiving policy. Further copying may not be permitted; contact the publisher for details.",

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AU - Bukvic, Alexander J

AU - Crivoi, Dana Georgiana

AU - Garwood, Hollie G

AU - McKay, Alasdair I

AU - Chen, Thomas T D

AU - Martínez-Martínez, Antonio J

AU - Weller, Andrew S

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AB - Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BArF4]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.

U2 - 10.1039/d0cc01140a

DO - 10.1039/d0cc01140a

M3 - Article

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SN - 1359-7345

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M1 - D0CC01140A

ER -

Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

Abstract

Bibliographical note

Access to Document

Projects

Putting Low Coordination into Practice by the Exploration of Metal-sigma-Interactions: Fundamentals, New Catalysts and Catalysis for New Materials

The Coordination Chemistry of Light Alkanes

Cite this