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From the same journal

Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer

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Author(s)

  • Alexander J Bukvic
  • Dana Georgiana Crivoi
  • Hollie G Garwood
  • Alasdair I McKay
  • Thomas T D Chen
  • Antonio J Martínez-Martínez
  • Andrew S Weller

Department/unit(s)

Publication details

JournalChemical communications
DateAccepted/In press - 5 Mar 2020
DateE-pub ahead of print (current) - 19 Mar 2020
Early online date19/03/20
Original languageEnglish

Abstract

Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BArF4]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.

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