Transannulation Reactions in the Synthesis of Natural Products

Paul A. Clarke, Andrew T. Reeder, Joby Winn

Research output: Contribution to journalLiterature reviewpeer-review

Abstract

An overview on the construction of polycyclic natural products by use of transannulation reactions across medium and large rings is presented.

Original languageEnglish
Pages (from-to)691-709
Number of pages19
JournalSYNTHESIS-STUTTGART
Issue number5
DOIs
Publication statusPublished - 2 Mar 2009

Keywords

  • transannulation
  • polycyclic
  • natural products
  • ASYMMETRIC TOTAL-SYNTHESIS
  • TRANS-ANNULAR CYCLIZATION
  • FORMAL TOTAL-SYNTHESIS
  • DIELS-ALDER REACTIONS
  • DEF-RING CORE
  • ENANTIOSELECTIVE SYNTHESIS
  • RADICAL CYCLIZATIONS
  • HEXACYCLINIC ACID
  • STRATEGY
  • CASCADE

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