Abstract
The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.
Original language | English |
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Pages (from-to) | 2859-2862 |
Number of pages | 4 |
Journal | JOURNAL OF ORGANOMETALLIC CHEMISTRY |
Volume | 691 |
Issue number | 13 |
DOIs | |
Publication status | Published - 15 Jun 2006 |
Keywords
- phosphaalkynes
- palladium
- clusters
- phosphinidene ligands
- MOLECULAR-STRUCTURE
- DIISOCYANIDE COMPLEXES
- CARBONYL CLUSTER
- CRYSTAL
- ALKYNE
- BOND
- 2,2-DIMETHYLPROPYLIDYNEPHOSPHINE
- COORDINATION
- TRIPALLADIUM
- ISOCYANIDE