Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand

C D  Andrews; A D  Burrows; M  Green; J M  Lynam; M F  Mahon

doi:10.1016/j.jorganchem.2006.03.014

Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand

C D Andrews, A D Burrows, M Green, J M Lynam, M F Mahon

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	2859-2862
Number of pages	4
Journal	JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume	691
Issue number	13
DOIs	https://doi.org/10.1016/j.jorganchem.2006.03.014
Publication status	Published - 15 Jun 2006

Keywords

phosphaalkynes
palladium
clusters
phosphinidene ligands
MOLECULAR-STRUCTURE
DIISOCYANIDE COMPLEXES
CARBONYL CLUSTER
CRYSTAL
ALKYNE
BOND
2,2-DIMETHYLPROPYLIDYNEPHOSPHINE
COORDINATION
TRIPALLADIUM
ISOCYANIDE

Access to Document

10.1016/j.jorganchem.2006.03.014

Cite this

@article{2f8c29e047a34a6389d061d6a10ad018,

title = "Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand",

abstract = "The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.",

keywords = "phosphaalkynes, palladium, clusters, phosphinidene ligands, MOLECULAR-STRUCTURE, DIISOCYANIDE COMPLEXES, CARBONYL CLUSTER, CRYSTAL, ALKYNE, BOND, 2,2-DIMETHYLPROPYLIDYNEPHOSPHINE, COORDINATION, TRIPALLADIUM, ISOCYANIDE",

author = "Andrews, {C D} and Burrows, {A D} and M Green and Lynam, {J M} and Mahon, {M F}",

year = "2006",

month = jun,

day = "15",

doi = "10.1016/j.jorganchem.2006.03.014",

language = "English",

volume = "691",

pages = "2859--2862",

journal = "JOURNAL OF ORGANOMETALLIC CHEMISTRY",

issn = "0022-328X",

publisher = "Elsevier",

number = "13",

}

TY - JOUR

T1 - Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand

AU - Andrews, C D

AU - Burrows, A D

AU - Green, M

AU - Lynam, J M

AU - Mahon, M F

PY - 2006/6/15

Y1 - 2006/6/15

N2 - The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.

AB - The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.

KW - phosphaalkynes

KW - palladium

KW - clusters

KW - phosphinidene ligands

KW - MOLECULAR-STRUCTURE

KW - DIISOCYANIDE COMPLEXES

KW - CARBONYL CLUSTER

KW - CRYSTAL

KW - ALKYNE

KW - BOND

KW - 2,2-DIMETHYLPROPYLIDYNEPHOSPHINE

KW - COORDINATION

KW - TRIPALLADIUM

KW - ISOCYANIDE

U2 - 10.1016/j.jorganchem.2006.03.014

DO - 10.1016/j.jorganchem.2006.03.014

M3 - Article

SN - 0022-328X

VL - 691

SP - 2859

EP - 2862

JO - JOURNAL OF ORGANOMETALLIC CHEMISTRY

JF - JOURNAL OF ORGANOMETALLIC CHEMISTRY

IS - 13

ER -