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Trifluoromethylthiolation of aromatic substrates using thiophosgene-fluoride salt reagents, and formation of byproducts with multi-carbon chains

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JournalJOURNAL OF FLUORINE CHEMISTRY
DatePublished - 4 Jun 1999
Issue number1-2
Volume95
Number of pages6
Pages (from-to)171-176
Original languageEnglish

Abstract

Reaction of potassium fluoride or tetramethylammonium fluoride with thiophosgene leads to the formation of a nucleophilic source of trifluoromethanethiolate, suitable for the preparation of trifluoromethyl aryl sulfides from activated haloaromatics. Analysis of the byproducts in the system demonstrates that complex molecules with up to C-4 chains may be formed by the reaction of fluoride salts with thiophosgene. (C) 1999 Elsevier Science S.A. All rights reserved.

    Research areas

  • trifluoromethylthio, tetramethylammonium fluoride (TMAF), dithiine, dithione, CHEMISTRY

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