TY - JOUR
T1 - Tris(3,6-dioxaheptyl)amine alkali-metal cation complexes. A fast atom bombardment mass spectrometry, infrared, and nuclear magnetic resonance study
AU - Miller, Jack M.
AU - Brown, Stephen J.
AU - Theberge, Roger
AU - Clark, James H.
PY - 1986/1/1
Y1 - 1986/1/1
N2 - Tris(3,6-dioxaheptyl)amine (tdoha, industrial name TDA-1) is shown to complex with a series of alkali-metal cations in solution, complexation being observed by fast atom bombardment mass spectrometry (f.a.b.m.s.; observation of a metal-tdoha cation), i.r., and 19F n.m.r. Approximate values of the relative concentrations of the tdoha and crown ether complexes are obtained by f.a.b.m.s. by competitive complexation experiments with a range of cations.
AB - Tris(3,6-dioxaheptyl)amine (tdoha, industrial name TDA-1) is shown to complex with a series of alkali-metal cations in solution, complexation being observed by fast atom bombardment mass spectrometry (f.a.b.m.s.; observation of a metal-tdoha cation), i.r., and 19F n.m.r. Approximate values of the relative concentrations of the tdoha and crown ether complexes are obtained by f.a.b.m.s. by competitive complexation experiments with a range of cations.
UR - http://www.scopus.com/inward/record.url?scp=37049071347&partnerID=8YFLogxK
U2 - 10.1039/DT9860002525
DO - 10.1039/DT9860002525
M3 - Article
AN - SCOPUS:37049071347
SN - 1472-7773
SP - 2525
EP - 2528
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 12
ER -