Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes

E A  Lewis; J R L  Smith; P H  Walton; S J  Archibald; S P  Foxon; G M P  Giblin

doi:10.1039/b102103f

Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes

E A Lewis, J R L Smith, P H Walton, S J Archibald, S P Foxon, G M P Giblin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A selection of 5-substituted salicylaldehydes have been reacted with cis,cis-triaminocyclohexane to prepare a series of tri-imine and tri-amine ligands; cyclic voltammetry has been used to show that the electronic effect of the substituent has a marked and systematic effect on the Mn-III/Mn-IV and Mn-III/Mn-II redox potentials of their manganese complexes.

Original language	English
Pages (from-to)	1159-1161
Number of pages	3
Journal	JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue number	8
DOIs	https://doi.org/10.1039/b102103f
Publication status	Published - 2001

Keywords

LIPOPHILIC HEXADENTATE ALUMINUM
SUPEROXIDE DISMUTASES
IRON COMPLEXES
IN-VIVO
COORDINATION
GALLIUM
LIGANDS
ENZYMES
INDIUM
WATER

Access to Document

10.1039/b102103f

Cite this

@article{e130bc8758b04c019d435883aaa73535,

title = "Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes",

abstract = "A selection of 5-substituted salicylaldehydes have been reacted with cis,cis-triaminocyclohexane to prepare a series of tri-imine and tri-amine ligands; cyclic voltammetry has been used to show that the electronic effect of the substituent has a marked and systematic effect on the Mn-III/Mn-IV and Mn-III/Mn-II redox potentials of their manganese complexes.",

keywords = "LIPOPHILIC HEXADENTATE ALUMINUM, SUPEROXIDE DISMUTASES, IRON COMPLEXES, IN-VIVO, COORDINATION, GALLIUM, LIGANDS, ENZYMES, INDIUM, WATER",

author = "Lewis, {E A} and Smith, {J R L} and Walton, {P H} and Archibald, {S J} and Foxon, {S P} and Giblin, {G M P}",

year = "2001",

doi = "10.1039/b102103f",

language = "English",

pages = "1159--1161",

journal = "JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS",

issn = "1472-7773",

publisher = "The Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes

AU - Lewis, E A

AU - Smith, J R L

AU - Walton, P H

AU - Archibald, S J

AU - Foxon, S P

AU - Giblin, G M P

PY - 2001

Y1 - 2001

N2 - A selection of 5-substituted salicylaldehydes have been reacted with cis,cis-triaminocyclohexane to prepare a series of tri-imine and tri-amine ligands; cyclic voltammetry has been used to show that the electronic effect of the substituent has a marked and systematic effect on the Mn-III/Mn-IV and Mn-III/Mn-II redox potentials of their manganese complexes.

AB - A selection of 5-substituted salicylaldehydes have been reacted with cis,cis-triaminocyclohexane to prepare a series of tri-imine and tri-amine ligands; cyclic voltammetry has been used to show that the electronic effect of the substituent has a marked and systematic effect on the Mn-III/Mn-IV and Mn-III/Mn-II redox potentials of their manganese complexes.

KW - LIPOPHILIC HEXADENTATE ALUMINUM

KW - SUPEROXIDE DISMUTASES

KW - IRON COMPLEXES

KW - IN-VIVO

KW - COORDINATION

KW - GALLIUM

KW - LIGANDS

KW - ENZYMES

KW - INDIUM

KW - WATER

U2 - 10.1039/b102103f

DO - 10.1039/b102103f

M3 - Article

SN - 1472-7773

SP - 1159

EP - 1161

JO - JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS

JF - JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS

IS - 8

ER -