By the same authors

From the same journal

Unexpected cleavage of upper rim-bridged calix[4]arenes leading to linear oligophenolic derivatives

Research output: Contribution to journalArticle

Published copy (DOI)

Author(s)

Department/unit(s)

Publication details

JournalOrganic and Biomolecular Chemistry
DateAccepted/In press - 4 Jan 2018
DateE-pub ahead of print (current) - 4 Jan 2018
Issue number5
Volume16
Number of pages6
Pages (from-to)838-843
Early online date4/01/18
Original languageEnglish

Abstract

Regioselective meta-mercuration followed by Pd-catalysed intramolecular bridging gave birth to a novel type of calixarene bearing a single bond bridge between the meta positions of the neighboring aromatic subunits. These bridged derivatives possess extremely distorted cavities that imply possible amended properties over common calix[4]arenes. This new type of calixarene reactivity can be documented by acid-/electrophile-mediated cleavage of the basic macrocyclic skeleton leading to open oligomeric structures - the behavior of which has never been observed before in classic calix[4]arenes bearing alkoxy groups on the lower rim.

Discover related content

Find related publications, people, projects, datasets and more using interactive charts.

View graph of relations