Unexpected, photochemically induced activation of the tetrabutylammonium cation by hexachloroplatinate(iv)

Imelda H. Silalahi; Navpreet K. Sethi; Marsel Z. Shafikov; Victor Chechik; Adrian C. Whitwood; Duncan W. Bruce

doi:10.1039/c8cc06423g

Unexpected, photochemically induced activation of the tetrabutylammonium cation by hexachloroplatinate(iv)

Imelda H. Silalahi, Navpreet K. Sethi, Marsel Z. Shafikov, Victor Chechik, Adrian C. Whitwood, Duncan W. Bruce^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A dinuclear, butadiene-bridged complex, trans-μ²:η²,η²-1,3-butadiene-bis(trichloroplatinate(ii)) (1) was unexpectedly obtained on photolysis of acetone solutions of (NBu₄)₂[PtCl₆].

Original language	English
Pages (from-to)	13682-13685
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	97
Early online date	2 Nov 2018
DOIs	https://doi.org/10.1039/c8cc06423g
Publication status	Published - 18 Dec 2018

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©The Royal Society of Chemistry 2018. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

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title = "Unexpected, photochemically induced activation of the tetrabutylammonium cation by hexachloroplatinate(iv)",

abstract = "A dinuclear, butadiene-bridged complex, trans-μ2:η2,η2-1,3-butadiene-bis(trichloroplatinate(ii)) (1) was unexpectedly obtained on photolysis of acetone solutions of (NBu4)2[PtCl6].",

author = "Silalahi, {Imelda H.} and Sethi, {Navpreet K.} and Shafikov, {Marsel Z.} and Victor Chechik and Whitwood, {Adrian C.} and Bruce, {Duncan W.}",

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AU - Silalahi, Imelda H.

AU - Sethi, Navpreet K.

AU - Shafikov, Marsel Z.

AU - Chechik, Victor

AU - Whitwood, Adrian C.

AU - Bruce, Duncan W.

N1 - ©The Royal Society of Chemistry 2018. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details.

PY - 2018/12/18

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N2 - A dinuclear, butadiene-bridged complex, trans-μ2:η2,η2-1,3-butadiene-bis(trichloroplatinate(ii)) (1) was unexpectedly obtained on photolysis of acetone solutions of (NBu4)2[PtCl6].

AB - A dinuclear, butadiene-bridged complex, trans-μ2:η2,η2-1,3-butadiene-bis(trichloroplatinate(ii)) (1) was unexpectedly obtained on photolysis of acetone solutions of (NBu4)2[PtCl6].

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DO - 10.1039/c8cc06423g

M3 - Article

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VL - 54

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JO - Chemical Communications

JF - Chemical Communications

IS - 97

ER -

Unexpected, photochemically induced activation of the tetrabutylammonium cation by hexachloroplatinate(iv)

Abstract

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