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Unexpected side products in the tetramethylammonium fluoride-dimethylsulphoxide system

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JournalJOURNAL OF FLUORINE CHEMISTRY
DatePublished - 11 Feb 1999
Issue number1
Volume94
Number of pages5
Pages (from-to)51-55
Original languageEnglish

Abstract

Reactions of chloro- and nitro-aromatics with low water content solutions of TMAF in DMSO can lead to complex product mixtures resulting from activation of DMSO by fluoride and the formation of DMSO-derived products. Also, the system has been shown to give hydrolysis products in addition to the well-known ethers and phenols, with carboxylic acids and benzamides being formed from the attempted fluorodenitration of substituted benzonitriles. (C) 1999 Elsevier Science S.A. All rights reserved.

    Research areas

  • tetramethylammonium fluoride, dimethylsulphoxide, base catalysis, diphenylmethane, benzonitrile, ORGANIC-SYNTHESIS, ARYL FLUORIDES, CHLORIDE, ION

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