Research output: Contribution to journal › Article › peer-review
Journal | Organic and Biomolecular Chemistry |
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Date | Published - 14 Aug 2015 |
Issue number | 30 |
Volume | 13 |
Number of pages | 12 |
Pages (from-to) | 8298-8309 |
Original language | English |
Pd-mediated C-H bond functionalisation protocols have been designed and developed on tryptophan derivatives and tryptophan-containing peptides. The examination of different arylation reactions (three sets of different conditions A-C), all of which are notable for their low temperatures (≤40°C), allowed identification of unified and complementary synthetic approaches toward a series of functionalised tryptophan-containing products. Tryptophan-containing peptides demonstrated to be susceptible to aromatic oxidation were successfully and selectively modified through the application of diaryliodonium salts in good yields.
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