Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo(VI) centres of Ru(II)–Mo(VI) dyads

Maryam Nazari Haghighi Pashaki; Tae-Kyu Choi; Egmont Rohwer; Thomas  Feurer; Anne-Kathrin Duhme-Klair; Wojciech Gawelda; Andrea Cannizzo

doi:10.1039/d1cc00750e

Unveiling the origin of photo-induced enhancement of oxidation catalysis at Mo(VI) centres of Ru(II)–Mo(VI) dyads

Maryam Nazari Haghighi Pashaki, Tae-Kyu Choi, Egmont Rohwer, Thomas Feurer, Anne-Kathrin Duhme-Klair, Wojciech Gawelda, Andrea Cannizzo

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Photo-induced oxidation-enhancement in biomimetic bridged Ru(II)–Mo(VI) photo-catalyst is unexpectedly photo-activated in ps timescales. One-photon absorption generates an excited state where both photo-oxidized and photo-reduced catalytic centres are activated simultaneously and independently.

Original language	English
Pages (from-to)	4142-4145
Number of pages	4
Journal	Chemical communications
Volume	57
Issue number	34
Early online date	23 Mar 2021
DOIs	https://doi.org/10.1039/d1cc00750e
Publication status	Published - 30 Apr 2021

Bibliographical note

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d1cc00750e
© The Royal Society of Chemistry 2021
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Cite this

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abstract = "Photo-induced oxidation-enhancement in biomimetic bridged Ru(II)–Mo(VI) photo-catalyst is unexpectedly photo-activated in ps timescales. One-photon absorption generates an excited state where both photo-oxidized and photo-reduced catalytic centres are activated simultaneously and independently.",

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AU - Nazari Haghighi Pashaki, Maryam

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AU - Rohwer, Egmont

AU - Feurer, Thomas

AU - Duhme-Klair, Anne-Kathrin

AU - Gawelda, Wojciech

AU - Cannizzo, Andrea

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AB - Photo-induced oxidation-enhancement in biomimetic bridged Ru(II)–Mo(VI) photo-catalyst is unexpectedly photo-activated in ps timescales. One-photon absorption generates an excited state where both photo-oxidized and photo-reduced catalytic centres are activated simultaneously and independently.

U2 - 10.1039/d1cc00750e

DO - 10.1039/d1cc00750e

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